Document Detail


Microwave-promoted facile and efficient preparation of N-(alkoxycarbonylmethyl) nucleobases--building blocks for peptide nucleic acids.
MedLine Citation:
PMID:  17851409     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
A simple, rapid, and regioselective approach for the synthesis of N-(methoxy-carbonylmethyl)- and N-(n-propoxycarbonylmethyl) nucleobases was developed. By using DMF as the solvent and in the presence of K2CO3 as the base, all the desired products were obtained in moderate yields within 8 min under microwave irradiation.
Authors:
Guirong Qu; Zhiguang Zhang; Haiming Guo; Mingwei Geng; Ran Xia
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't     Date:  2007-03-19
Journal Detail:
Title:  Molecules (Basel, Switzerland)     Volume:  12     ISSN:  1420-3049     ISO Abbreviation:  Molecules     Publication Date:  2007  
Date Detail:
Created Date:  2007-09-13     Completed Date:  2007-10-23     Revised Date:  2009-10-27    
Medline Journal Info:
Nlm Unique ID:  100964009     Medline TA:  Molecules     Country:  Switzerland    
Other Details:
Languages:  eng     Pagination:  543-51     Citation Subset:  IM    
Affiliation:
College of Chemistry and Environmental Science, Henan Normal University, Xinxiang 453007, PR China. quguir@163.com
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MeSH Terms
Descriptor/Qualifier:
Alkylation
Cytosine / analogs & derivatives*,  chemical synthesis,  chemistry
Dimethylformamide
Microwaves*
Peptide Nucleic Acids / chemistry*
Purines / chemical synthesis*,  chemistry
Thymine / analogs & derivatives*,  chemical synthesis,  chemistry
Time Factors
Uracil / analogs & derivatives,  chemistry
Chemical
Reg. No./Substance:
0/Peptide Nucleic Acids; 0/Purines; 65-71-4/Thymine; 66-22-8/Uracil; 68-12-2/Dimethylformamide; 71-30-7/Cytosine

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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