Document Detail


Microwave-assisted synthesis of carbon nanodots through an eggshell membrane and their fluorescent application.
MedLine Citation:
PMID:  23037913     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Carbon nanodots (C-Dots) as a new form of carbonaceous nanomaterials have aroused much interest and intensive research due to their inspiring properties. Compared to traditional semiconductor quantum dots, these newly emergent nanodots possess a number of advantageous characteristics, among which low-toxicity is particularly fascinating. More and more research into C-Dots have focused on synthesis methods and biology-related applications. Microwave-assisted approaches have attracted attention because microwave treatment can provide intensive and efficient energy, and as a consequence shorten the reaction time. In this article, we designed a "green", rapid, eco-friendly and waste-reused approach to synthesize fluorescent and water-soluble C-Dots from eggshell membrane (ESM) ashes according to a microwave-assisted process. ESM selected as the carbon source was a common protein-rich waste in daily life and can be obtained easily and cheaply. The C-Dots from our method showed the maximal fluorescence emission peak at 450 nm and the fluorescence quantum yield was about 14%. We further designed a sensitive probe for glutathione based on the fluorescence turn off and on of the C-Dots-Cu(2+) system, which showed a linear range of 0.5-80 μmol L(-1) and detection limit of 0.48 μmol L(-1). In general, the C-Dots prepared briefly and inexpensively from ESM revealed excellent fluorescent property with promising potential for applications such as sample detection and biotechnology.
Authors:
Qi Wang; Xing Liu; Lichun Zhang; Yi Lv
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-10-5
Journal Detail:
Title:  The Analyst     Volume:  -     ISSN:  1364-5528     ISO Abbreviation:  Analyst     Publication Date:  2012 Oct 
Date Detail:
Created Date:  2012-10-5     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0372652     Medline TA:  Analyst     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu, Sichuan 610064, China. lvy@scu.edu.cn.
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