Document Detail


Microwave-assisted Cu-catalyzed protodecarboxylation of aromatic carboxylic acids.
MedLine Citation:
PMID:  19239228     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
An effective protocol has been developed that allows the smooth protodecarboxylation of diversely functionalized aromatic carboxylic acids within 5-15 min. In the presence of at most 5 mol % of an inexpensive catalyst generated in situ from copper(I) oxide and 1,10-phenanthroline, even nonactivated benzoates were converted in high yields and with great preparative ease.
Authors:
Lukas J Goossen; Filipe Manjolinho; Bilal A Khan; Nuria Rodríguez
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  The Journal of organic chemistry     Volume:  74     ISSN:  1520-6904     ISO Abbreviation:  J. Org. Chem.     Publication Date:  2009 Mar 
Date Detail:
Created Date:  2009-03-16     Completed Date:  2009-04-30     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  2985193R     Medline TA:  J Org Chem     Country:  United States    
Other Details:
Languages:  eng     Pagination:  2620-3     Citation Subset:  IM    
Affiliation:
Fachbereich Chemie, Technische Universitat Kaiserslautern, Erwin-Schroedinger-Strasse, D-67663 Kaiserslautern, Germany. goossen@chemie.uni-kl.de
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MeSH Terms
Descriptor/Qualifier:
Benzoic Acids / chemistry
Carboxylic Acids / chemistry*
Catalysis
Copper*
Decarboxylation
Microwaves
Phenanthrolines / chemistry
Photochemical Processes
Chemical
Reg. No./Substance:
0/Benzoic Acids; 0/Carboxylic Acids; 0/Phenanthrolines; 66-71-7/1,10-phenanthroline; 7440-50-8/Copper

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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