| Michael reactions of titanium enolates of glycolic acid derivatives with the Weinreb and morpholine amides of acrylic acid. | |
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MedLine Citation:
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PMID: 18198888 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
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The conjugate additions of titanium enolates of glycolate-derived chiral oxazolidin-2-ones to various Michael acceptors have been evaluated as an entry to enantiopure 1,2,5-trioxygenated and related synthons. alpha,beta-unsaturated Weinreb and morpholine amides do react under suitable conditions and their adducts can be converted to diverse C1-C5 chiral fragments. |
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Authors:
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Anna Olivella; Carles Rodríguez-Escrich; Fèlix Urpí; Jaume Vilarrasa |
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Publication Detail:
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Type: Journal Article; Research Support, Non-U.S. Gov't Date: 2008-01-17 |
Journal Detail:
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Title: The Journal of organic chemistry Volume: 73 ISSN: 0022-3263 ISO Abbreviation: J. Org. Chem. Publication Date: 2008 Feb |
Date Detail:
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Created Date: 2008-02-08 Completed Date: 2008-05-05 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 2985193R Medline TA: J Org Chem Country: United States |
Other Details:
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Languages: eng Pagination: 1578-81 Citation Subset: IM |
Affiliation:
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Departament de Química Orgànica, Facultat de Química, Universitat de Barcelona, 08028 Barcelona, Catalonia, Spain. |
Export Citation:
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| MeSH Terms | |
Descriptor/Qualifier:
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Acrylates
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chemistry* Amides / chemistry* Glycolates / chemistry* Magnetic Resonance Spectroscopy Mass Spectrometry Morpholines / chemistry* Spectrophotometry, Infrared Titanium / chemistry* |
| Chemical | |
Reg. No./Substance:
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0/Acrylates; 0/Amides; 0/Glycolates; 0/Morpholines; 7440-32-6/Titanium; 79-10-7/acrylic acid; 79-14-1/glycolic acid |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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