| Metal-only Lewis pairs featuring unsupported Pt→M (M = Zn or Cd) dative bonds. | |
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MedLine Citation:
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PMID: 23149548 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Reactions of [Pt(PCy(3))(2)] (Cy = cyclohexyl) with group 12 metal dihalides have afforded the novel metal only Lewis pair (MOLP) complexes, [(Cy(3)P)(2)Pt→MX(2)] (M = Zn or Cd, X = Br or I), or the oxidative addition product, trans-[(Cy(3)P)(2)(I)PtHgI]. The zinc complex represents the first MOLP to contain an unsupported Pt→Zn linkage. |
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Authors:
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Mengtao Ma; Anastas Sidiropoulos; Lalrempuia Ralte; Andreas Stasch; Cameron Jones |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-11-14 |
Journal Detail:
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Title: Chemical communications (Cambridge, England) Volume: - ISSN: 1364-548X ISO Abbreviation: Chem. Commun. (Camb.) Publication Date: 2012 Nov |
Date Detail:
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Created Date: 2012-11-14 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9610838 Medline TA: Chem Commun (Camb) Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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School of Chemistry, Monash University, PO Box 23, Melbourne, VIC 3800, Australia. cameron.jones@monash.edu andreas.stasch@monash.edu. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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