Document Detail

Metal-catalyzed rearrangements of 3-allenyl 3-hydroxyindolin-2-ones in the presence of halogenated reagents.
MedLine Citation:
PMID:  23314199     Owner:  NLM     Status:  Publisher    
The reactions of 3-allenyl 3-hydroxyoxindoles with a variety of halogenated reagents in the presence of catalytic amounts of precious metal salts were explored. Both, rearrangement and oxycyclization reactions to give 4-(1-halovinyl)-quinolinediones or spirocyclic halooxindoles, respectively, are competitive pathways. The kind of functionalization is substrate and reaction conditions dependent.
Benito Alcaide; Pedro Almendros; Amparo Luna; Natividad Prieto
Related Documents :
24596099 - Metal-containing carbonyl ylides: versatile reactants in catalytic enantioselective cas...
20619399 - Novel 2'-hydroxylfurylchalcones: synthesis and biological activity.
23251909 - Metagenomic approach in the investigation of new bioactive compounds in the marine envi...
24214519 - Bioinspired total synthesis of montanine-type amaryllidaceae alkaloids.
23740869 - Stereodivergent synthesis of piperidine alkaloids by ring-rearrangement metathesis/redu...
22996259 - Pickering emulsion stabilized by catalytic polyoxometalate nanoparticles: a new effecti...
17338539 - Enantioselective total synthesis of 1-epi-pathylactone a.
21638489 - Chain transfer to polymer and branching in controlled radical polymerizations of n-buty...
25364859 - Silicon directed rhenium catalyzed allylic substitutions with n-hydroxycarbamates, n-hy...
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-1-14
Journal Detail:
Title:  Organic & biomolecular chemistry     Volume:  -     ISSN:  1477-0539     ISO Abbreviation:  Org. Biomol. Chem.     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-1-14     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101154995     Medline TA:  Org Biomol Chem     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Grupo de Lactamas y Heterociclos Bioactivos, Departamento de Química Orgánica I, Unidad Asociada al CSIC, Facultad de Química, Universidad Complutense de Madrid, 28040-Madrid, Spain.
Export Citation:
APA/MLA Format     Download EndNote     Download BibTex
MeSH Terms

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine

Previous Document:  Analysis of PIK3CA exon 9 and 20 mutations in breast cancers using PCR-HRM and PCR-ARMS: Correlation...
Next Document:  Urinary environmental chemical concentrations and vitamin D are associated with vision, hearing, and...