| Metal-Mediated Synthesis of 1,4-Di-tert-butyl-1,4-azaborine. | |
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MedLine Citation:
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PMID: 22952191 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Completing the set: Although 1,2-azaborine is known, little is known about the 1,3- and 1,4-analogues. Now a simple, controlled synthesis of 1,2-di-tert-butyl-1,2-azaborine from acetylene and di-tert-butyliminoborane has been achieved by a metal-mediated formal [2+2+2] cycloaddition reaction. A 1,2-azaborete pianostool complex was identified as an reaction intermediate. |
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Authors:
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Holger Braunschweig; Alexander Damme; J Oscar C Jimenez-Halla; Bernd Pfaffinger; Krzysztof Radacki; Justin Wolf |
Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-9-5 |
Journal Detail:
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Title: Angewandte Chemie (International ed. in English) Volume: - ISSN: 1521-3773 ISO Abbreviation: Angew. Chem. Int. Ed. Engl. Publication Date: 2012 Sep |
Date Detail:
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Created Date: 2012-9-6 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 0370543 Medline TA: Angew Chem Int Ed Engl Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Copyright Information:
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Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
Affiliation:
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Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg (Germany) http://www-anorganik.chemie.uni-wuerzburg.de/Braunschweig/index.html. h.braunschweig@mail.uni-wuerzburg.de. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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