Document Detail

Metal-Free, Aerobic Dioxygenation of Alkenes Using Simple Hydroxamic Acid Derivatives.
MedLine Citation:
PMID:  21809867     Owner:  NLM     Status:  Publisher    
The dioxygenation of alkenes using molecular oxygen and a simple hydroxamic acid derivative has been achieved. The reaction system is comprised of readily-prepared methyl N-hydroxy(phenyl)carbamate and molecular oxygen with a catalytic amount of a radical initiator, and offers an alternative to common precious transition-metal-catalyzed dioxygenation processes. This transformation capitalizes on the unique reactivity profile of hydroxamic acid derivatives in radical-mediated alkene addition processes.
Benjamin C Giglio; Valerie Anne Schmidt; Erik John Alexanian
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2011-8-2
Journal Detail:
Title:  Journal of the American Chemical Society     Volume:  -     ISSN:  1520-5126     ISO Abbreviation:  -     Publication Date:  2011 Aug 
Date Detail:
Created Date:  2011-8-3     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  7503056     Medline TA:  J Am Chem Soc     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
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