Document Detail


Metal-Free, Aerobic Dioxygenation of Alkenes Using Simple Hydroxamic Acid Derivatives.
MedLine Citation:
PMID:  21809867     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The dioxygenation of alkenes using molecular oxygen and a simple hydroxamic acid derivative has been achieved. The reaction system is comprised of readily-prepared methyl N-hydroxy(phenyl)carbamate and molecular oxygen with a catalytic amount of a radical initiator, and offers an alternative to common precious transition-metal-catalyzed dioxygenation processes. This transformation capitalizes on the unique reactivity profile of hydroxamic acid derivatives in radical-mediated alkene addition processes.
Authors:
Benjamin C Giglio; Valerie Anne Schmidt; Erik John Alexanian
Related Documents :
17710667 - Biliary reflux and non-acid reflux are two distinct phenomena: a comparison between 24-...
16484967 - New horizons in the medical treatment of gastro-oesophageal reflux disease.
15131567 - Microbial exposure of rural school children, as assessed by levels of n-acetyl-muramic ...
8306147 - Changes in acid-base balance and calcium metabolism after urinary diversion through ile...
16991187 - Highly regioselective rhodium-catalysed hydroformylation of unsaturated esters: the fir...
5945247 - The localization of lysosomal enzymes in chromaffin tissue.
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2011-8-2
Journal Detail:
Title:  Journal of the American Chemical Society     Volume:  -     ISSN:  1520-5126     ISO Abbreviation:  -     Publication Date:  2011 Aug 
Date Detail:
Created Date:  2011-8-3     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  7503056     Medline TA:  J Am Chem Soc     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Export Citation:
APA/MLA Format     Download EndNote     Download BibTex
MeSH Terms
Descriptor/Qualifier:

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


Previous Document:  Reaction Dynamics of a Molecular Switch Unveiled by Coherent Two-Dimensional Electronic Spectroscopy...
Next Document:  Water Exchange Reactivity and Stability of Cobalt Polyoxometalates under Catalytically Relevant pH C...