| Metal-Free, Aerobic Dioxygenation of Alkenes Using Simple Hydroxamic Acid Derivatives. | |
| | |
MedLine Citation:
|
PMID: 21809867 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
|
The dioxygenation of alkenes using molecular oxygen and a simple hydroxamic acid derivative has been achieved. The reaction system is comprised of readily-prepared methyl N-hydroxy(phenyl)carbamate and molecular oxygen with a catalytic amount of a radical initiator, and offers an alternative to common precious transition-metal-catalyzed dioxygenation processes. This transformation capitalizes on the unique reactivity profile of hydroxamic acid derivatives in radical-mediated alkene addition processes. |
| | |
Authors:
|
Benjamin C Giglio; Valerie Anne Schmidt; Erik John Alexanian |
Related Documents
:
|
17710667 - Biliary reflux and non-acid reflux are two distinct phenomena: a comparison between 24-... 16484967 - New horizons in the medical treatment of gastro-oesophageal reflux disease. 15131567 - Microbial exposure of rural school children, as assessed by levels of n-acetyl-muramic ... 8306147 - Changes in acid-base balance and calcium metabolism after urinary diversion through ile... 16991187 - Highly regioselective rhodium-catalysed hydroformylation of unsaturated esters: the fir... 5945247 - The localization of lysosomal enzymes in chromaffin tissue. |
Publication Detail:
|
Type: JOURNAL ARTICLE Date: 2011-8-2 |
Journal Detail:
|
Title: Journal of the American Chemical Society Volume: - ISSN: 1520-5126 ISO Abbreviation: - Publication Date: 2011 Aug |
Date Detail:
|
Created Date: 2011-8-3 Completed Date: - Revised Date: - |
Medline Journal Info:
|
Nlm Unique ID: 7503056 Medline TA: J Am Chem Soc Country: - |
Other Details:
|
Languages: ENG Pagination: - Citation Subset: - |
Export Citation:
|
APA/MLA Format Download EndNote Download BibTex |
| MeSH Terms | |
Descriptor/Qualifier:
|
|
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
Previous Document: Reaction Dynamics of a Molecular Switch Unveiled by Coherent Two-Dimensional Electronic Spectroscopy...
Next Document: Water Exchange Reactivity and Stability of Cobalt Polyoxometalates under Catalytically Relevant pH C...