Document Detail

Mechanism of visible-light photoisomerization of a rhenium(I) carbonyl-diimine complex.
MedLine Citation:
PMID:  20877849     Owner:  NLM     Status:  In-Process    
The mechanism of photoisomerization of a Re(I) carbonyl-diimine complex under visible-light irradiation is deciphered by means of ab initio calculations. By highlighting the key role of triplet states as well as spin-orbit and vibronic couplings, we provide a clear picture of this complicated multi-step process.
Etienne Gindensperger; Horst Köppel; Chantal Daniel
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Publication Detail:
Type:  Journal Article     Date:  2010-09-28
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  46     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2010 Nov 
Date Detail:
Created Date:  2010-10-27     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  England    
Other Details:
Languages:  eng     Pagination:  8225-7     Citation Subset:  -    
Laboratoire de Chimie Quantique, CNRS-Université de Strasbourg, Institut de Chimie UMR 7177, 4, rue Blaise Pascal, F-67070 Strasbourg Cedex, France.
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