Document Detail


Measurements of weak halogen bond donor abilities with tridentate anion receptors.
MedLine Citation:
PMID:  21052594     Owner:  NLM     Status:  In-Process    
Abstract/OtherAbstract:
The chelate effect of a tridentate receptor is exploited to determine halogen bonding association constants that vary by several orders of magnitude, including interactions of weak donors for which thermodynamic data were not previously available. Free energy relationships with computed and experimental properties hold over this wide range of donors. The strengths of iodine- and bromine-based halogen bonds, CH-anion and anion-arene interactions are compared.
Authors:
Elena Dimitrijević; Olga Kvak; Mark S Taylor
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Publication Detail:
Type:  Journal Article     Date:  2010-11-04
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  46     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2010 Dec 
Date Detail:
Created Date:  2010-11-24     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  England    
Other Details:
Languages:  eng     Pagination:  9025-7     Citation Subset:  -    
Affiliation:
Department of Chemistry, University of Toronto, 80 St. George St., Toronto, ON M5S 3H6, Canada.
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