| Measured effects of various electrolyte and capillary properties in dielectric barrier electrospray ionization - Development of a comprehensive model. | |
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MedLine Citation:
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PMID: 23046012 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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The mechanism which leads to a dielectric barrier electrospray (DB-ES) was investigated by measurements of the electrical current. It comprises several components, namely the displacement current, currents which are initiated by electromagnetic transmission, an ion current inside the capillary which is responsible for the built-up of the potential at the tip, and the electrospray current as a result of the displacement current and the ion transfer current. An augmented interpretation of the current signal of the DB-ES is presented and features are described in more detail. The behaviour of the ions inside the capillary and the charge transfer are described from the chemical and the electrical point of view. |
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Authors:
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Irina Reginskaya; Ann-Kathrin Stark; Michael Schilling; Dirk Janasek; Joachim Franzke |
Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-10-9 |
Journal Detail:
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Title: Analytical chemistry Volume: - ISSN: 1520-6882 ISO Abbreviation: Anal. Chem. Publication Date: 2012 Oct |
Date Detail:
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Created Date: 2012-10-10 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 0370536 Medline TA: Anal Chem Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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