Document Detail

Making practical use of the pseudo-element concept: an efficient way to ternary intermetalloid clusters by an isoelectronic Pb(-)-Bi combination.
MedLine Citation:
PMID:  22962663     Owner:  NLM     Status:  Publisher    
Syntheses of [K([2.2.2]crypt)](+) salts of binary Pb-Bi Zintl anions and their reaction with ZnPh(2) or Ni(cod)(2), yielding ternary intermetalloid Ni-Pb-Bi or Zn-Pb-Bi clusters, proved the use of binary precursors with fully isoelectronic atoms as an efficient and thus valuable synthetic approach to this class of clusters. (207)Pb NMR and ESI mass spectra provided insight into the solution behavior of the binary or ternary cages.
Rodica Ababei; Johanna Heine; Małgorzata Hołyńska; Günther Thiele; Bastian Weinert; Xiulan Xie; Florian Weigend; Stefanie Dehnen
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-9-10
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2012 Sep 
Date Detail:
Created Date:  2012-9-10     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Fachbereich Chemie and Wissenschaftliches Zentrum für Materialwissenschaften (WZMW), Philipps-Universität Marburg, Hans-Meerwein-Straße, 35043 Marburg, Germany.
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