| Magnetic Anisotropy in a Dysprosium/DOTA Single-Molecule Magnet: Beyond Simple Magneto-Structural Correlations. | |
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MedLine Citation:
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PMID: 22241599 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Magnetic moments: The orientation of the title single-molecule magnet was investigated by magnetic single crystal and luminescence characterization, supported by ab initio calculations, and was found to be governed by the position of the hydrogen atoms of the apical water molecules. This finding suggests that simple magneto-structural correlations can give misleading clues for research in molecular magnetism as well as in MRI contrast agents design. |
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Authors:
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Giuseppe Cucinotta; Mauro Perfetti; Javier Luzon; Mael Etienne; Pierre-Emmanuel Car; Andrea Caneschi; Guillaume Calvez; Kevin Bernot; Roberta Sessoli |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-1-12 |
Journal Detail:
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Title: Angewandte Chemie (International ed. in English) Volume: - ISSN: 1521-3773 ISO Abbreviation: - Publication Date: 2012 Jan |
Date Detail:
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Created Date: 2012-1-13 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 0370543 Medline TA: Angew Chem Int Ed Engl Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Copyright Information:
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Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
Affiliation:
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Department of Chemistry "Ugo Schiff" and INSTM RU University of Florence, 50019 Sesto Fiorentino (Italy). |
Export Citation:
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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