| Macromolecular helicity inversion of an optically active helical poly(phenylacetylene) by chemical modification of the side groups. | |
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MedLine Citation:
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PMID: 17844743 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
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An optically active helical poly(phenylacetylene) was synthesized by the copolymerization of phenylacetylenes bearing optically active hydroxy or ester groups obtained by the kinetic resolution of a racemic phenylacetylene with lipase; the helix-sense was inverted from one helix to another by the further chemical modification of the hydroxy groups with achiral bulky isocyanates or an acid chloride. |
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Authors:
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Shinzo Kobayashi; Kazuhide Morino; Eiji Yashima |
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Publication Detail:
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Type: Journal Article; Research Support, Non-U.S. Gov't |
Journal Detail:
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Title: Chemical communications (Cambridge, England) Volume: - ISSN: 1359-7345 ISO Abbreviation: Chem. Commun. (Camb.) Publication Date: 2007 Jun |
Date Detail:
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Created Date: 2007-09-11 Completed Date: 2007-10-25 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9610838 Medline TA: Chem Commun (Camb) Country: England |
Other Details:
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Languages: eng Pagination: 2351-3 Citation Subset: IM |
Affiliation:
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Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University, Chikusa-ku, Nagoya 464-8603, Japan. |
Export Citation:
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| MeSH Terms | |
Descriptor/Qualifier:
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Acetylene
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analogs & derivatives*,
chemistry Kinetics Magnetic Resonance Spectroscopy Stereoisomerism |
| Chemical | |
Reg. No./Substance:
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0/poly(phenylacetylene); 74-86-2/Acetylene |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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