Document Detail


MOFs for CO(2) capture and separation from flue gas mixtures: the effect of multifunctional sites on their adsorption capacity and selectivity.
MedLine Citation:
PMID:  23150882     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Microporous metal-organic frameworks (MOFs) have attracted tremendous attention because of their versatile structures and tunable porosity that allow almost unlimited ways to improve their properties and optimize their functionality, making them very promising for a variety of important applications, especially in the adsorption and separation of small gases and hydrocarbons. Numerous studies have demonstrated that MOFs with multifunctional groups, such as open metal sites (OMSs) and Lewis basic sites (LBSs), interact strongly with carbon dioxide and are particularly effective in its capture and separation from binary mixtures of CO(2) and N(2). In this feature article, we briefly review the current state of MOF development in this area, with an emphasis on the effect of multifunctional groups on the selectivity and capacity of MOFs for the CO(2) capture from flue gas mixtures.
Authors:
Zhijuan Zhang; Yonggang Zhao; Qihan Gong; Zhong Li; Jing Li
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-11-14
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2012 Nov 
Date Detail:
Created Date:  2012-11-14     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, New Jersey 08854, USA. Jingli@rutgers.edu.
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