Document Detail


Luminescent bichromophoric spiroindolones - synthesis and electronic properties.
MedLine Citation:
PMID:  21796319     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Novel bichromophoric spirocyclic indolones have been synthesized by an insertion-coupling-isomerization-Diels-Alder domino reaction. The emission colors are strongly affected by the substituents: N-Boc leads to intense blue fluorescence, N-dansyl causes turquoise emission, whereas a 1-anthryl substituent on the butadiene results in yellow luminescence. The latter behavior is rationalized by TDDFT computations as a result of significant geometrical changes.
Authors:
Jan Schönhaber; Thomas J J Müller
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2011-7-28
Journal Detail:
Title:  Organic & biomolecular chemistry     Volume:  -     ISSN:  1477-0539     ISO Abbreviation:  -     Publication Date:  2011 Jul 
Date Detail:
Created Date:  2011-7-28     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101154995     Medline TA:  Org Biomol Chem     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Lehrstuhl für Organische Chemie, Institut für Organische Chemie und Makromolekulare Chemie, Heinrich-Heine-Universität Düsseldorf, Universitätsstraße 1, D-40225, Düsseldorf, Germany. ThomasJJ.Mueller@uni-duesseldorf.de.
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