Document Detail


Linoleic acid 10-hydroperoxide as an intermediate during formation of 1-octen-3-ol from linoleic acid in Lentinus decadetes.
MedLine Citation:
PMID:  14586122     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
In order to confirm the biosynthetic pathway to 1-octen-3-ol from linoleic acid, a crude enzyme solution was prepared from the edible mushroom, Lentinus decadetes. When the reaction was performed in the presence of glutathione peroxidase, which can reduce organic hydroperoxide to the corresponding hydroxide, the amount of 1-octen-3-ol formed from linoleic acid was decreased. At the same time, an accumulation of linoleic acid 10-hydroxide could be detected. The 10-hydroperoxide therefore seems to be an intermediate on the biosynthetic pathway.
Authors:
Kenji Matsui; Satomi Sasahara; Yoshihiko Akakabe; Tadahiko Kajiwara
Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Bioscience, biotechnology, and biochemistry     Volume:  67     ISSN:  0916-8451     ISO Abbreviation:  Biosci. Biotechnol. Biochem.     Publication Date:  2003 Oct 
Date Detail:
Created Date:  2003-10-30     Completed Date:  2004-07-26     Revised Date:  2004-11-17    
Medline Journal Info:
Nlm Unique ID:  9205717     Medline TA:  Biosci Biotechnol Biochem     Country:  Japan    
Other Details:
Languages:  eng     Pagination:  2280-2     Citation Subset:  IM    
Affiliation:
Department of Biological Chemistry, Faculty of Agriculture, Yamaguchi University, Yamaguchi, Japan. matsui@yamaguchi-u.ac.jp
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MeSH Terms
Descriptor/Qualifier:
Glutathione Peroxidase / metabolism
Hydrogen Peroxide / metabolism
Lentinula / metabolism*
Linoleic Acid / metabolism*
Octanols / metabolism*
Chemical
Reg. No./Substance:
0/Octanols; 2197-37-7/Linoleic Acid; 3391-86-4/1-octen-3-ol; 7722-84-1/Hydrogen Peroxide; EC 1.11.1.9/Glutathione Peroxidase

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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