Document Detail


Lichens--photophysical studies of potential new sunscreens.
MedLine Citation:
PMID:  19179091     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Fundamental photophysical properties have been obtained for six polyaromatics, calycine, usnic acid, vicanicine, 1-Cl-pannerine and epiphorelic acids I and II, extracted from Antarctic lichens--potential future sunscreens. None of the lichen compounds produced a measurable amount of triplet states and the singlet oxygen quantum yield was also very low ranging from 0.003 to 0.06. However, three exhibited triplet energy levels which may be above that of thymine. The radical cations of calycine and usnic acid were generated via pulse radiolysis and were observed to be quenched by vitamin C, vitamin E and Trolox.
Authors:
Fritz Boehm; Kristy Clarke; Ruth Edge; Ernesto Fernandez; Suppiah Navaratnam; Wanda Quilhot; Fiorenza Rancan; T George Truscott
Publication Detail:
Type:  Journal Article     Date:  2008-12-24
Journal Detail:
Title:  Journal of photochemistry and photobiology. B, Biology     Volume:  95     ISSN:  1873-2682     ISO Abbreviation:  J. Photochem. Photobiol. B, Biol.     Publication Date:  2009 Apr 
Date Detail:
Created Date:  2009-03-18     Completed Date:  2009-07-15     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  8804966     Medline TA:  J Photochem Photobiol B     Country:  Switzerland    
Other Details:
Languages:  eng     Pagination:  40-5     Citation Subset:  IM    
Affiliation:
Department of Dermatology, Humboldt University, 10117 Berlin, Germany.
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MeSH Terms
Descriptor/Qualifier:
Benzofurans / chemistry*,  isolation & purification,  radiation effects
Free Radicals / chemistry,  radiation effects
Lichens / chemistry*
Photolysis
Pulse Radiolysis
Quantum Theory
Singlet Oxygen / metabolism
Spectrophotometry, Ultraviolet
Sunscreening Agents / chemistry*,  isolation & purification,  radiation effects
Chemical
Reg. No./Substance:
0/Benzofurans; 0/Free Radicals; 0/Sunscreening Agents; 17778-80-2/Singlet Oxygen

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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