Document Detail


Layer-by-layer assembled MoO(2)-graphene thin film as a high-capacity and binder-free anode for lithium-ion batteries.
MedLine Citation:
PMID:  22744734     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Thin films of MoO(2) nanoparticles and graphene sheets are created by layer-by-layer (LBL) assembly as binder-free anodes for lithium-ion batteries. Both anionic polyoxometalate clusters and graphene oxide nanosheets with oxygen functional groups on both basal planes and edges are assembled into LBL films with the aid of a cationic polyelectrolyte. After a subsequent thermal treatment in an Ar-H(2) atmosphere, hybrid MoO(2)-graphene films with three-dimensionally interconnected nanopores are formed, which comprise ultrafine MoO(2) nanoparticles homogeneously embedded in the porous network of graphene nanosheets. When used as an anode for lithium-ion batteries, the MoO(2)-graphene thin-film electrode shows superior electrochemical performance with high specific capacity and excellent cyclability. A high specific capacity of 675.9 mA h g(-1) after 100 discharge-charge cycles is achieved, indicating a promising anode candidate for lithium-storage applications.
Authors:
Fangfang Xia; Xianluo Hu; Yongming Sun; Wei Luo; Yunhui Huang
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-6-29
Journal Detail:
Title:  Nanoscale     Volume:  -     ISSN:  2040-3372     ISO Abbreviation:  -     Publication Date:  2012 Jun 
Date Detail:
Created Date:  2012-6-29     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101525249     Medline TA:  Nanoscale     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
State Key Laboratory of Material Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. China. huxl@mail.hust.edu.cn xlhu07@gmail.com huangyh@mail.hust.edu.cn.
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