| LaSr(3)F(5)(CN(2))(2): A Prototype Structure for Mixed-Valent Eu(4)F(5)(CN(2))(2). | |
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MedLine Citation:
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PMID: 23153168 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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The new compound LaSr(3)F(5)(CN(2))(2) was prepared and structurally characterized as a prototype structure for the remarkably distorted mixed-valent compound Eu(4)F(5)(CN(2))(2), which contains four distinct europium ions in the structure: one Eu(3+) and three Eu(2+). Instead of repeating the given distorted structural pattern, LaSr(3)F(5)(CN(2))(2) forms a structure which can be considered as an ideal high-symmetry structure for Eu(4)F(5)(CN(2))(2), due to the occupation of La(3+) and Sr(2+) ions on one and the same crystallographic position. The crystal symmetry of this structure is an interesting issue to compare with what has been previously proposed. |
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Authors:
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Leonid Unverfehrt; Markus Ströbele; H-Jürgen Meyer |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-11-15 |
Journal Detail:
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Title: Inorganic chemistry Volume: - ISSN: 1520-510X ISO Abbreviation: Inorg Chem Publication Date: 2012 Nov |
Date Detail:
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Created Date: 2012-11-16 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 0366543 Medline TA: Inorg Chem Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Abteilung für Festkörperchemie und Theoretische Chemie, Institut für Anorganische Chemie, Universität Tübingen , Auf der Morgenstelle 18, D-72076 Tübingen, Germany. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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