Document Detail


Kinetic resolution of racemic 2,3-allenoates by organocatalytic asymmetric 1,3-dipolar cycloaddition.
MedLine Citation:
PMID:  20715835     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
The kinetic resolution of racemic 2,3-allenoates was realized via 1,3-dipolar cycloaddition by using a bisphosphoric acid catalyst, affording the optically active 2,3-allenoates and 3-methylenepyrrolidine derivatives in high yields and enantioselectivities.
Authors:
Jie Yu; Wei-Jie Chen; Liu-Zhu Gong
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  Organic letters     Volume:  12     ISSN:  1523-7052     ISO Abbreviation:  Org. Lett.     Publication Date:  2010 Sep 
Date Detail:
Created Date:  2010-09-10     Completed Date:  2010-12-21     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100890393     Medline TA:  Org Lett     Country:  United States    
Other Details:
Languages:  eng     Pagination:  4050-3     Citation Subset:  IM    
Affiliation:
Hefei National Laboratory for Physical Sciences at the Microscale and Department of Chemistry, University of Science and Technology of China, Hefei 230026, China.
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MeSH Terms
Descriptor/Qualifier:
Catalysis
Cyclization
Kinetics
Models, Molecular
Molecular Structure
Naphthalenes / chemistry*
Stereoisomerism
Chemical
Reg. No./Substance:
0/Naphthalenes; 553-39-9/allenolic acid

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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