Document Detail


Isolation of an sigma-alkyl iridium hydride complex, formed in the (semi)hydrogenation of an beta-enamidoketone.
MedLine Citation:
PMID:  23451978     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
sigma-Alkyl iridium hydride complexes are generally postulated as intermediates in iridium-catalyzed hydrogenation. Fast reductive elimination results in the formation of the hydrogenation product. With an beta-enamidoketone as unsaturated substrate, such an intermediate could be trapped, because the semihydrogenated product coordinates trifold to the iridium, generating a stable 18e--complex, which does not eliminate.
Authors:
Frauke Maurer; Uli Kazmaier
Related Documents :
23790448 - Metal concentrations in sediments from tourist beaches of miri city, sarawak, malaysia ...
24406818 - The directing effect of linking units on building microporous architecture in tetraphen...
23351038 - Inverse solvent isotope effects arising from substrate triggering in the factor inhibit...
23248988 - An effective structure prediction method for layered materials based on 2d particle swa...
21202418 - 1,2-bis[n'-(2,2-dimethyl-propionyl)thio-ureido]cyclo-hexa-ne.
25077958 - Simple cathode design for li-s batteries: cell performance and mechanistic insights by ...
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-3-4
Journal Detail:
Title:  The Journal of organic chemistry     Volume:  -     ISSN:  1520-6904     ISO Abbreviation:  J. Org. Chem.     Publication Date:  2013 Mar 
Date Detail:
Created Date:  2013-3-4     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  2985193R     Medline TA:  J Org Chem     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Export Citation:
APA/MLA Format     Download EndNote     Download BibTex
MeSH Terms
Descriptor/Qualifier:

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


Previous Document:  Influence of diverse chemical modifications on the ADME characteristics and toxicology of antisense ...
Next Document:  Abundance of Apple Maggot, Rhagoletis pomonella, Across Different Areas in Central Washington, with ...