Document Detail


Isolation and partial characterization of a novel amino sugar-containing fucan sulfate from commercial Fucus vesiculosus fucoidan.
MedLine Citation:
PMID:  8181008     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Commercial crude fucoidan (Sigma) from the brown seaweed Fucus vesiculosus was fractionated into its polysaccharide components by gel filtration and anion-exchange chromatography to clarify the structure-anticoagulant activity relationship. The products comprised a wide spectrum of fucans ranging from typical fucoidans (major components) containing mainly fucose, sulfate, and no uronic acid to low sulfate-containing heteropolysaccharide-like fucans (minor components) being composed of neutral sugars other than fucose and a high content of uronic acid(s). The polysaccharide components also had a wide range of molecular weight. The typical fucoidans showed a potent anticoagulant activity, whereas the other fucans had no or only slight activity. One of the fractions found as a minor component, was a novel polysaccharide containing an appreciable amount (11.5%) of glucosamine and a small amount (5.2%) of protein in addition to fucose and sulfate, and having a low apparent molecular weight of 6800. This is the first report that a proteoglycan-like, amino sugar-containing fucan sulfate, composed of fucose, galactose, glucose, mannose, xylose, uronic acid, glucosamine, and sulfate in the molar ratio of 1.00:0.04:0.01:0.48:0.24:0.18:0.56:1.90, could be obtained from brown seaweed. However, this polysaccharide showed no anticoagulant activity.
Authors:
T Nishino; C Nishioka; H Ura; T Nagumo
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  Carbohydrate research     Volume:  255     ISSN:  0008-6215     ISO Abbreviation:  Carbohydr. Res.     Publication Date:  1994 Mar 
Date Detail:
Created Date:  1994-06-14     Completed Date:  1994-06-14     Revised Date:  2006-11-15    
Medline Journal Info:
Nlm Unique ID:  0043535     Medline TA:  Carbohydr Res     Country:  NETHERLANDS    
Other Details:
Languages:  eng     Pagination:  213-24     Citation Subset:  IM    
Affiliation:
Department of Biophysics, School of Hygienic Sciences, Kitasato University, Kanagawa, Japan.
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MeSH Terms
Descriptor/Qualifier:
Algae, Brown / chemistry*
Amino Sugars / chemistry*
Anticoagulants / chemistry*
Polysaccharides / chemistry*
Proteoglycans / chemistry*
Sulfuric Acid Esters
Chemical
Reg. No./Substance:
0/Amino Sugars; 0/Anticoagulants; 0/Polysaccharides; 0/Proteoglycans; 0/Sulfuric Acid Esters; 9072-19-9/fucoidan

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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