| Iron promoted conjugate addition: implication of the six-centered mechanism based on the isolation of the iron-enolate intermediate. | |
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MedLine Citation:
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PMID: 23147813 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Treatment of (η(1)-mesityl)(2)Fe(κ(2)-TMEDA) () with an α,β-unsaturated carbonyl compound results in 1,4-addition of the mesityl group to give an iron enolate quantitatively. The Z-configuration of the enolate suggested the six-centered mechanism for the conjugate addition. |
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Authors:
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Daisuke Noda; Yusuke Sunada; Takuji Hatakeyama; Masaharu Nakamura; Hideo Nagashima |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-11-12 |
Journal Detail:
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Title: Chemical communications (Cambridge, England) Volume: - ISSN: 1364-548X ISO Abbreviation: Chem. Commun. (Camb.) Publication Date: 2012 Nov |
Date Detail:
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Created Date: 2012-11-13 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9610838 Medline TA: Chem Commun (Camb) Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Graduate School of Engineering Sciences, Kyushu University, 6-1 Kasugakoen, Kasuga, Fukuoka, 816-8580, Japan. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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