Document Detail


Iron promoted conjugate addition: implication of the six-centered mechanism based on the isolation of the iron-enolate intermediate.
MedLine Citation:
PMID:  23147813     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Treatment of (η(1)-mesityl)(2)Fe(κ(2)-TMEDA) () with an α,β-unsaturated carbonyl compound results in 1,4-addition of the mesityl group to give an iron enolate quantitatively. The Z-configuration of the enolate suggested the six-centered mechanism for the conjugate addition.
Authors:
Daisuke Noda; Yusuke Sunada; Takuji Hatakeyama; Masaharu Nakamura; Hideo Nagashima
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-11-12
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2012 Nov 
Date Detail:
Created Date:  2012-11-13     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Graduate School of Engineering Sciences, Kyushu University, 6-1 Kasugakoen, Kasuga, Fukuoka, 816-8580, Japan.
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