| Iron-mediated one-pot formal nitrocyclization onto unactivated alkenes. | |
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MedLine Citation:
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PMID: 21088775 Owner: NLM Status: In-Data-Review |
Abstract/OtherAbstract:
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One-pot synthesis of heterocycles having a nitromethyl group was achieved by sequential steps that involved chloronitration of alkenes using iron(iii) nitrate nonahydrate followed by elimination and intramolecular Michael addition. This reaction provides an efficient method for the synthesis of heterocycles due to the simple experimental procedure and the use of inexpensive reagents of low toxicity. |
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Authors:
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Tsuyoshi Taniguchi; Tatsuya Fujii; Hiroyuki Ishibashi |
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Publication Detail:
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Type: Journal Article Date: 2010-11-18 |
Journal Detail:
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Title: Organic & biomolecular chemistry Volume: 9 ISSN: 1477-0539 ISO Abbreviation: Org. Biomol. Chem. Publication Date: 2011 Feb |
Date Detail:
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Created Date: 2011-01-20 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 101154995 Medline TA: Org Biomol Chem Country: England |
Other Details:
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Languages: eng Pagination: 653-5 Citation Subset: IM |
Affiliation:
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School of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical and Health Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan. tsuyoshi@p.kanazawa-u.ac.jp. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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