Document Detail

Ionic liquid buffers: a new class of chemicals with potential for controlling pH in non-aqueous media.
MedLine Citation:
PMID:  17082864     Owner:  NLM     Status:  MEDLINE    
Ionic liquids with buffering characteristics, synthesized by the reaction of [RMIM]OH base moieties with phthalic and tartaric acid, respectively, are potential reagents for controlling pH in non-aqueous media; remarkable [Base]/[Acid] molar ratio dependence of the catalytic activities has been observed in the hydrogenation of olefins with [RuCl2(PPh3)3] complex in DMF and [BMIM][BF4].
Guang-nan Ou; Ming-xia Zhu; Jia-rong She; You-zhu Yuan
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't     Date:  2006-10-18
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1359-7345     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2006 Nov 
Date Detail:
Created Date:  2006-11-03     Completed Date:  2007-01-19     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  England    
Other Details:
Languages:  eng     Pagination:  4626-8     Citation Subset:  IM    
State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
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MeSH Terms
Hydrogen-Ion Concentration
Imidazoles / chemical synthesis,  chemistry*
Ionic Liquids / chemical synthesis,  chemistry*
Molecular Structure
Phthalic Acids / chemistry
Tartrates / chemistry
Reg. No./Substance:
0/Buffers; 0/Imidazoles; 0/Ionic Liquids; 0/Phthalic Acids; 0/Tartrates; 526-83-0/tartaric acid; 88-99-3/phthalic acid

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