Document Detail


Inverse-Micelle-Encapsulated Water-Enabled Bond Breaking of Dialkyl-Diselenide/Disulfide: a Critical Step for Synthesiz-ing High-Quality Au Nanoparticles.
MedLine Citation:
PMID:  23046420     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Inverse-micelle-encapsulated water formed in the two-phase Brust-Schiffrin method (BSM) synthesis of Au nanoparticles (NPs) is identified as essential for dialkyl diselenide/disulfide to react with the Au(III) complex in which the Se-Se/S-S bond is broken, leading to formation of higher-quality Au NPs.
Authors:
Oksana Zaluzhna; Ying Li; Thomas C Allison; Yuye J Tong
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-10-9
Journal Detail:
Title:  Journal of the American Chemical Society     Volume:  -     ISSN:  1520-5126     ISO Abbreviation:  J. Am. Chem. Soc.     Publication Date:  2012 Oct 
Date Detail:
Created Date:  2012-10-10     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  7503056     Medline TA:  J Am Chem Soc     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
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