Document Detail


Intramolecular energy transfer in a one-dimensional europium tetracyanoplatinate.
MedLine Citation:
PMID:  18271536     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
The one-dimensional, polymeric compound (C15H11N3)Eu(H2O)2(NO3)(Pt(CN)4).CH3CN (1) has been shown to display an efficient donor-acceptor intramolecular energy-transfer (IET) process where ligand donors transfer energy to the Eu (III) acceptor. Single-crystal X-ray diffraction has been used to investigate the structural features of this compound in order to help understand the observed IET process. Crystallographic data: 1, monoclinic, space group P2(1)/c, a = 12.835(1) A, b = 15.239(1) A, c = 13.751(2) A, beta = 105.594(9) degrees , V = 2590.8(5) A(3), and Z = 4 (T = 290 K).
Authors:
Branson A Maynard; Katrina Kalachnikova; Kendra Whitehead; Zerihun Assefa; Richard E Sykora
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Publication Detail:
Type:  Journal Article     Date:  2008-02-14
Journal Detail:
Title:  Inorganic chemistry     Volume:  47     ISSN:  0020-1669     ISO Abbreviation:  Inorg Chem     Publication Date:  2008 Mar 
Date Detail:
Created Date:  2008-03-13     Completed Date:  2008-05-20     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0366543     Medline TA:  Inorg Chem     Country:  United States    
Other Details:
Languages:  eng     Pagination:  1895-7     Citation Subset:  -    
Affiliation:
Department of Chemistry, University of South Alabama, Mobile, Alabama 36688, USA.
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