Document Detail


The Intercalation of N,N,N',N'-Tetramethyl-ethane-1,2-diamine (tmeda) into C(6)Li and C(12)Li.
MedLine Citation:
PMID:  22468729     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Liquid N,N,N',N'-tetramethyl-ethane-1,2-diamine (tmeda) was intercalated into preprepared C(6)Li or C(12)Li. X-ray diffraction from the ternary compound indicates an identity period of 11.5 Å. The (13)C NMR line shifts show that tmeda molecules form a screen between the graphene planes and the lithium ions. Small-angle X-ray scattering showed that no higher structural ordering was present but revealed a progressive roughening of the surfaces with successive intercalation of lithium and amine into the graphite galleries.
Authors:
Mark J Henderson; Takatoshi Nishimura; John W White
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-4-2
Journal Detail:
Title:  Inorganic chemistry     Volume:  -     ISSN:  1520-510X     ISO Abbreviation:  -     Publication Date:  2012 Apr 
Date Detail:
Created Date:  2012-4-3     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0366543     Medline TA:  Inorg Chem     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Research School of Chemistry, Australian National University , Canberra ACT 0200, Australia.
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