| Insertion of benzyne into the Pd-C bond. Synthesis of unnatural amino acid derivatives by sequential insertion of benzyne and CO: 2,2'-functionalized biaryls containing alkylamino and carboxymethyl substituents. Isolation of stable carbopalladated-benzyne intermediates. | |
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MedLine Citation:
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PMID: 22644258 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Reaction of ortho-palladated derivatives of phentermine and homoveratrylamine with benzyne allows the synthesis of enlarged eight-membered palladacycles resulting from the insertion of the aryne into the Pd-C bond, which subsequently react with CO, to render unnatural amino acid derivatives. |
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Authors:
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José-Antonio García-López; María-José Oliva-Madrid; Isabel Saura-Llamas; Delia Bautista; José Vicente |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-5-29 |
Journal Detail:
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Title: Chemical communications (Cambridge, England) Volume: - ISSN: 1364-548X ISO Abbreviation: - Publication Date: 2012 May |
Date Detail:
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Created Date: 2012-5-30 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9610838 Medline TA: Chem Commun (Camb) Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Grupo de Química Organometálica, Departamento de Química Inorgánica, Facultad de Química, Universidad de Murcia, Aptdo. 4021, E-30071 Murcia, Spain. joangalo@um.es mjoliva@um.es ims@um.es jvs1@um.es. |
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