Document Detail


The Influence of Neighboring Group Participation on the Hydrolysis of 2-O-Substituted Methyl Glucopyranosides.
MedLine Citation:
PMID:  22007683     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Does neighboring group participation actually enhance the reactivity of the anomeric center when the participating group is inherently disarming? To investigate the influence of the neighboring group effect from a 2-O protective group on acidic glycoside hydrolysis, 10 methyl glucosides having different protective groups on O2 have been synthesized and a clear trend between anomeric configuration, participation of the protective group, and the rate of hydrolysis could be observed.
Authors:
Mads Heuckendorff; Christian M Pedersen; Mikael Bols
Related Documents :
2080363 - Stereotactic evacuation and fibrinolysis of cerebellar hematomas.
1808653 - Stereotactic helium ion bragg peak radiosurgery for intracranial arteriovenous malforma...
3480953 - Prostaglandin e2 in tylose gel for cervical ripening before induction of labor.
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2011-10-18
Journal Detail:
Title:  Organic letters     Volume:  -     ISSN:  1523-7052     ISO Abbreviation:  -     Publication Date:  2011 Oct 
Date Detail:
Created Date:  2011-10-19     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100890393     Medline TA:  Org Lett     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Universitetsparken 5, DK-2100 Copenhagen O, Denmark.
Export Citation:
APA/MLA Format     Download EndNote     Download BibTex
MeSH Terms
Descriptor/Qualifier:

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


Previous Document:  TiO(2) nanoparticles induce insulin resistance in liver-derived cells both directly and via macropha...
Next Document:  Outcomes following kinesthetic feedback for gait training in a direct access environment: A case rep...