| Induction of diastereoselectivity in Fe(II) tris(amino acid-bipyridine) complexes. | |
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MedLine Citation:
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PMID: 11463248 Owner: NLM Status: PubMed-not-MEDLINE |
Abstract/OtherAbstract:
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A group of iron(II) tris-bipyridine complexes bearing L-amino acids (L-Lys, L-Phe, L-Ser, L-Val) was prepared to investigate the predetermination of chirality of metal complexes by the chiral amino acid subunits. Noncovalent interactions and solvent polarity seemed to be important factors in inducing diastereoselectivity of the metal complexes. These phenomena were explained by (1)H NMR and CD spectroscopic studies and molecular mechanics calculations. |
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Authors:
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D R Ahn; T W Kim; J I Hong |
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Publication Detail:
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Type: Journal Article |
Journal Detail:
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Title: The Journal of organic chemistry Volume: 66 ISSN: 0022-3263 ISO Abbreviation: J. Org. Chem. Publication Date: 2001 Jul |
Date Detail:
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Created Date: 2001-07-20 Completed Date: 2001-08-30 Revised Date: 2003-10-31 |
Medline Journal Info:
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Nlm Unique ID: 2985193R Medline TA: J Org Chem Country: United States |
Other Details:
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Languages: eng Pagination: 5008-11 Citation Subset: - |
Affiliation:
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School of Chemistry and Molecular Engineering, College of Natural Sciences, Seoul National University, Seoul, 151-747, Korea. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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