Document Detail


In situ measurement of exciton energy in hybrid singlet-fission solar cells.
MedLine Citation:
PMID:  22910365     Owner:  NLM     Status:  In-Data-Review    
Abstract/OtherAbstract:
Singlet exciton fission-sensitized solar cells have the potential to exceed the Shockley-Queisser limit by generating additional photocurrent from high-energy photons. Pentacene is an organic semiconductor that undergoes efficient singlet fission-the conversion of singlet excitons into pairs of triplets. However, the pentacene triplet is non-emissive, and uncertainty regarding its energy has hindered device design. Here we present an in situ measurement of the pentacene triplet energy by fabricating a series of bilayer solar cells with infrared-absorbing nanocrystals of varying bandgaps. We show that the pentacene triplet energy is at least 0.85 eV and at most 1.00 eV in operating devices. Our devices generate photocurrent from triplets, and achieve external quantum efficiencies up to 80%, and power conversion efficiencies of 4.7%. This establishes the general use of nanocrystal size series to measure the energy of non-emissive excited states, and suggests that fission-sensitized solar cells are a favourable candidate for third-generation photovoltaics.
Authors:
Bruno Ehrler; Brian J Walker; Marcus L Böhm; Mark W B Wilson; Yana Vaynzof; Richard H Friend; Neil C Greenham
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Nature communications     Volume:  3     ISSN:  2041-1723     ISO Abbreviation:  Nat Commun     Publication Date:  2012 Aug 
Date Detail:
Created Date:  2012-08-22     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101528555     Medline TA:  Nat Commun     Country:  England    
Other Details:
Languages:  eng     Pagination:  1019     Citation Subset:  IM    
Affiliation:
Cavendish Laboratory, J.J. Thomson Avenue, University of Cambridge, Cambridge CB3 0HE, UK.
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