Document Detail

Improving catalytic activity by synergic effect between base and acid pairs in hierarchically porous chitosan@titania nanoreactors.
MedLine Citation:
PMID:  20121161     Owner:  NLM     Status:  PubMed-not-MEDLINE    
The beneficial effect of the bifunctional character of the chitosan@titania hybrid in heterogeneous catalysis was elucidated: considering a prototypical Henry condensation, Michael addition, and Jasminaldehyde synthesis, the cohabitation of a basic site (NH(2)) and an acidic site (Ti) in the same reactor provided clear activity and selectivity enhancements, with respect to the monofunctional acidic titania and basic chitosan counterparts.
Abdelkrim El Kadib; Karine Molvinger; Mosto Bousmina; Daniel Brunel
Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Organic letters     Volume:  12     ISSN:  1523-7052     ISO Abbreviation:  Org. Lett.     Publication Date:  2010 Mar 
Date Detail:
Created Date:  2010-03-01     Completed Date:  2010-05-20     Revised Date:  2010-05-21    
Medline Journal Info:
Nlm Unique ID:  100890393     Medline TA:  Org Lett     Country:  United States    
Other Details:
Languages:  eng     Pagination:  948-51     Citation Subset:  -    
Institut Charles Gerhardt, UMR 5253 CNRS/ENSCM/UM2/UM1, 8 rue de l'Ecole Normale, 34296 Montpellier Cedex 5, France.
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Erratum In:
Org Lett. 2010 May 21;12(10):2446

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