| Imidazolinium and amidinium salts as Lewis acid organocatalysts. | |
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MedLine Citation:
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PMID: 23209514 Owner: NLM Status: PubMed-not-MEDLINE |
Abstract/OtherAbstract:
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The application of imidazolinium and amidinium salts as soft Lewis acid organocatalysts is described. These salts were suitable catalysts for the activation of unsaturated thioesters in a Diels-Alder reaction and in the ring opening of thiiranes and epoxides. The products were isolated in good yields. The mild catalysts did not cause desulfurization of the products containing a thiol or thiocarbonyl group. |
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Authors:
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Oksana Sereda; Nicole Clemens; Tatjana Heckel; René Wilhelm |
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Publication Detail:
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Type: Journal Article Date: 2012-10-18 |
Journal Detail:
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Title: Beilstein journal of organic chemistry Volume: 8 ISSN: 1860-5397 ISO Abbreviation: Beilstein J Org Chem Publication Date: 2012 |
Date Detail:
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Created Date: 2012-12-04 Completed Date: 2012-12-05 Revised Date: 2013-03-01 |
Medline Journal Info:
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Nlm Unique ID: 101250746 Medline TA: Beilstein J Org Chem Country: Germany |
Other Details:
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Languages: eng Pagination: 1798-803 Citation Subset: - |
Affiliation:
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Institute of Organic Chemistry, Clausthal University of Technology, 38678 Clausthal-Zellerfeld, Germany. |
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