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Hydrothermal synthesis of an ortho-metallated Co(iii) complex anchored by a carboxylate group with a selective oxidation catalytic property.
MedLine Citation:
PMID:  23348750     Owner:  NLM     Status:  Publisher    
An air-stable and water-tolerant ortho-metallated complex [Co(tfb)(bpy)(2)](NO(3))·3H(2)O was obtained via hydrothermal synthesis. The mechanism for the formation of Co-C bond was studied using both DFT calculations and experimental analysis. This highly stable complex exhibits good catalytic performance for the selective oxidation of cyclohexane.
Shi-Yuan Zhang; Wei Shi; Jian-Gong Ma; Yu-Qi Zhang; Zhen-Jie Zhang; Peng Cheng
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-1-25
Journal Detail:
Title:  Dalton transactions (Cambridge, England : 2003)     Volume:  -     ISSN:  1477-9234     ISO Abbreviation:  Dalton Trans     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-1-25     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101176026     Medline TA:  Dalton Trans     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Department of Chemistry and Key Laboratory of Advanced Energy Materials Chemistry (MOE), TKL of Metal and Molecule Based Material Chemistry, Nankai University, Tianjin 300071, P. R. China.
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