| Hydrogenation of C-C double bonds in an ionic liquid reaction system using the obligate anaerobe, Sporomusa termitida. | |
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MedLine Citation:
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PMID: 15717124 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
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Sporomusa termitida reduced caffeate (1mM) in anaerobic, two-liquid phase, reaction systems containing either tetradecane or 1-butyl-3-methylimidazolium hexafluorophosphate [[bmim][PF6]] (20% v/v). The initial rate and final product yield were 20 and 7% lower, respectively, in [bmim][PF6]. Since caffeate partitioned only into the aqueous phase, the lower rate cannot be attributed to mass transfer barriers. Therefore, [bmim][PF6] inhibited the biocatalyst, perhaps unsurprisingly since it is very polar and hydrolyses to produce HF. |
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Authors:
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Alix Lenourry; John M Gardiner; Gill Stephens |
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Publication Detail:
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Type: Journal Article |
Journal Detail:
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Title: Biotechnology letters Volume: 27 ISSN: 0141-5492 ISO Abbreviation: Biotechnol. Lett. Publication Date: 2005 Feb |
Date Detail:
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Created Date: 2005-02-17 Completed Date: 2005-09-06 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 8008051 Medline TA: Biotechnol Lett Country: Netherlands |
Other Details:
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Languages: eng Pagination: 161-5 Citation Subset: IM |
Affiliation:
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School of Chemical Engineering, University of Manchester, P.O. Box 88, Manchester M60 1QD, UK. |
Export Citation:
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APA/MLA Format Download EndNote Download BibTex |
| MeSH Terms | |
Descriptor/Qualifier:
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Alkanes
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chemistry,
metabolism Bacteria, Anaerobic / growth & development, metabolism* Biotransformation Carbon / chemistry, metabolism* Culture Media Hydrogenation Imidazoles / chemistry, metabolism Solvents / chemistry* Time Factors |
| Chemical | |
Reg. No./Substance:
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0/1-butyl-3-methylimidazolium hexafluorophosphate; 0/Alkanes; 0/Culture Media; 0/Imidazoles; 0/Solvents; 629-59-4/n-tetradecane; 7440-44-0/Carbon |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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