Document Detail


"Host-guest" interactions between non-micellized amphiphilic invertible polymer and insoluble cyclohexasilane in acetonitrile.
MedLine Citation:
PMID:  21797281     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
"Host-guest" interactions between amphiphilic invertible macromolecules based on PEG and sebacic acid, and cyclohexasilane (Si6H12) in acetonitrile (neither a solvent for cyclohexasilane, nor supporting micellization of amphiphilic invertible macromolecules) have been investigated. Despite the extended conformation of the AIP macromolecules and the absence of self-assembled polymeric domains, an AIP amphiphilicity itself contributes to localizing Si6H12 by AIP and, thus, enables Lewis acid-base interaction between Si6H12 and the AIP carbonyl groups. The obtained results demonstrate an interesting phenomenon that insoluble Si6H12 can be localized by AIP macromolecules in a medium which does not support formation of polymeric domains.
Authors:
Ananiy Kohut; Olena Kudina; Xuliang Dai; Douglas Lloyd Schulz; Andriy S Voronov
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2011-7-28
Journal Detail:
Title:  Langmuir : the ACS journal of surfaces and colloids     Volume:  -     ISSN:  1520-5827     ISO Abbreviation:  -     Publication Date:  2011 Jul 
Date Detail:
Created Date:  2011-7-29     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9882736     Medline TA:  Langmuir     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
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