| "Host-guest" interactions between non-micellized amphiphilic invertible polymer and insoluble cyclohexasilane in acetonitrile. | |
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MedLine Citation:
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PMID: 21797281 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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"Host-guest" interactions between amphiphilic invertible macromolecules based on PEG and sebacic acid, and cyclohexasilane (Si6H12) in acetonitrile (neither a solvent for cyclohexasilane, nor supporting micellization of amphiphilic invertible macromolecules) have been investigated. Despite the extended conformation of the AIP macromolecules and the absence of self-assembled polymeric domains, an AIP amphiphilicity itself contributes to localizing Si6H12 by AIP and, thus, enables Lewis acid-base interaction between Si6H12 and the AIP carbonyl groups. The obtained results demonstrate an interesting phenomenon that insoluble Si6H12 can be localized by AIP macromolecules in a medium which does not support formation of polymeric domains. |
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Authors:
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Ananiy Kohut; Olena Kudina; Xuliang Dai; Douglas Lloyd Schulz; Andriy S Voronov |
Publication Detail:
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Type: JOURNAL ARTICLE Date: 2011-7-28 |
Journal Detail:
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Title: Langmuir : the ACS journal of surfaces and colloids Volume: - ISSN: 1520-5827 ISO Abbreviation: - Publication Date: 2011 Jul |
Date Detail:
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Created Date: 2011-7-29 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9882736 Medline TA: Langmuir Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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