Document Detail


Homogeneous Catalysis of Valeronitrile Hydrolysis under Supercritical Conditions.
MedLine Citation:
PMID:  22190404     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Supercritical nitrile hydrolysis can be used for both, amide and acid production as well as waste water treatment, as the hydrolysis products show good biodegradability. The conventional process at ambient conditions requires large amounts of mineral acid or base. Approaches that use supercritical water as a green solvent without a catalyst have been investigated over recent years. Findings for valeronitrile hydrolysis presented recently showed promising reaction rates and valeric acid yields. In an attempt to further maximize product yield and to better understand the impact of the pH, reactions in dilute sulfuric acid (0.01 mol L(-1) ) were performed in a continuous high-pressure laboratory-scale apparatus at 400-500 °C, 30 MPa, and a maximum residence time of 100 s. Results from both reaction media were compared with regard to productivity and sustainability.
Authors:
Michael Sarlea; Sabine Kohl; Nina Blickhan; Herbert Vogel
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2011-12-20
Journal Detail:
Title:  ChemSusChem     Volume:  -     ISSN:  1864-564X     ISO Abbreviation:  -     Publication Date:  2011 Dec 
Date Detail:
Created Date:  2011-12-22     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101319536     Medline TA:  ChemSusChem     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
Ernst-Berl-Institut für Technische und Makromolekulare Chemie, Technische Universität Darmstadt, Petersenstrasse 20, 64287 Darmstadt (Germany), Fax: (+49) 6151-163465.
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