Document Detail


Highly practical amino acid and alkaloid synthesis using designer chiral phase transfer catalysts as high-performance organocatalysts.
MedLine Citation:
PMID:  20878639     Owner:  NLM     Status:  In-Process    
Abstract/OtherAbstract:
A series of chiral quaternary ammonium salts derived from commercially available (R)- or (S)-binaphthol have been designed as new C(2)-symmetric chiral phase transfer catalysts. In order to realize the flexible design of these phase transfer catalysts, the combinatorial design approach has been developed. These chiral high-performance organocatalysts have been successfully applied to the highly practical asymmetric synthesis of various amino acid derivatives including α-alkyl and α,α-dialkyl-α-amino acids in addition to alkaloids.
Authors:
Keiji Maruoka
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  Chemical record (New York, N.Y.)     Volume:  10     ISSN:  1528-0691     ISO Abbreviation:  Chem Rec     Publication Date:  2010 Oct 
Date Detail:
Created Date:  2010-10-14     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101085550     Medline TA:  Chem Rec     Country:  United States    
Other Details:
Languages:  eng     Pagination:  254-9     Citation Subset:  IM    
Copyright Information:
© 2010 The Japan Chemical Journal Forum and Wiley Periodicals, Inc.
Affiliation:
Department of Chemistry, Graduate School of Science, Kyoto University, Kyoto 606-8502, Japan. maruoka@kuchem.kyoto-u.ac.jp
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