| Highly enantioselective gamma-amination of alpha,beta-unsaturated acycl chlorides with azodicarboxylates. Efficient synthesis of chiral gamma-amino acid derivatives. | |
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MedLine Citation:
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PMID: 21902208 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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The cinchona alkaloids-catalyzed γ-amination of α,β-unsaturated acyl chlorides with azodicarboxylates was developed to give the corresponding dihydropyridazinones in good yields with high enantioselectivities. Reductive ring-opening of the dihydropyridazinones afforded series of cyclic and acyclic γ-amino acid derivatives in good yields with high enantiopurity. |
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Authors:
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Li-Tao Shen; Li-Hui Sun; Song Ye |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2011-9-8 |
Journal Detail:
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Title: Journal of the American Chemical Society Volume: - ISSN: 1520-5126 ISO Abbreviation: - Publication Date: 2011 Sep |
Date Detail:
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Created Date: 2011-9-9 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 7503056 Medline TA: J Am Chem Soc Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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