Document Detail


Highly efficient decomposition of organic dye by aqueous-solid phase transfer & in situ photocatalysis using hierarchical copper phthalocyanine hollow-sphere.
MedLine Citation:
PMID:  21678935     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The hierarchical tetranitro copper phthalocyanine (TNCuPc) hollow spheres were fabricated by a simple solvothermal method. The formation mechanism was proposed based on the evolution of morphology as a function of solvothermal time, which involved the initial formation of nanoparticles followed by their self-aggregation to microspheres and transformation into hierarchical hollow spheres by Ostwald ripening. Furthermore, the hierarchical TNCuPc hollow spheres exhibited high adsorption capacity and excellent simultaneously visible-light-driven photocatalytic performance for Rhodamine B (RB) under visible-light. A possible mechanism for the "aqueous-solid phase transfer and in situ photocatalysis" was suggested. Repetitive tests showed that the hierarchical TNCuPc hollow spheres maintained high catalytic activity over several cycles, and it had a better regeneration capability under mild conditions.
Authors:
Mingyi Zhang; Changlu Shao; Zengcai Guo; Zhenyi Zhang; Jingbo Mu; Peng Zhang; Tieping Cao; Yichun Liu
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2011-6-16
Journal Detail:
Title:  ACS applied materials & interfaces     Volume:  -     ISSN:  1944-8252     ISO Abbreviation:  -     Publication Date:  2011 Jun 
Date Detail:
Created Date:  2011-6-17     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101504991     Medline TA:  ACS Appl Mater Interfaces     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
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