Document Detail


Highly active, immobilized ruthenium catalysts for oxidation of alcohols to aldehydes and ketones. Preparation and use in both batch and flow systems.
MedLine Citation:
PMID:  15969605     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
A novel, highly active immobilized ruthenium catalyst, which can be successfully used in oxidation of alcohols to aldehydes and ketones, has been developed. In contrast to most immobilized catalysts, the Ru catalyst has activity that is higher than that of the original non-immobilized catalyst. In a batch system, the Ru catalyst was recovered and reused several times without loss of activity. The catalyst was also applied to a flow system, in which excellent conversions and yields were demonstrated. No leaching of Ru was observed in both cases.
Authors:
Shu Kobayashi; Hiroyuki Miyamura; Ryo Akiyama; Tasuku Ishida
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  Journal of the American Chemical Society     Volume:  127     ISSN:  0002-7863     ISO Abbreviation:  J. Am. Chem. Soc.     Publication Date:  2005 Jun 
Date Detail:
Created Date:  2005-06-22     Completed Date:  2005-10-26     Revised Date:  2006-11-15    
Medline Journal Info:
Nlm Unique ID:  7503056     Medline TA:  J Am Chem Soc     Country:  United States    
Other Details:
Languages:  eng     Pagination:  9251-4     Citation Subset:  IM    
Affiliation:
Graduate School of Pharmaceutical Sciences, The University of Tokyo, The HFRE Division, ERATO, Japan Science and Technology Agency (JST), Hongo, Bunkyo-ku, Tokyo 113-0033, Japan. skobayas@mol.f.u-tokyo.ac.jp
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MeSH Terms
Descriptor/Qualifier:
Alcohols / chemistry*
Aldehydes / chemical synthesis*
Catalysis
Ketones / chemical synthesis*
Molecular Structure
Organometallic Compounds / chemistry*
Oxidation-Reduction
Ruthenium / chemistry*
Chemical
Reg. No./Substance:
0/Alcohols; 0/Aldehydes; 0/Ketones; 0/Organometallic Compounds; 7440-18-8/Ruthenium

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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