Document Detail


Highly Enantioselective Reduction of β-Amino Nitroolefins with a Simple N-Sulfinyl Urea as Bifunctional Catalyst.
MedLine Citation:
PMID:  22736502     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Simple but effective: A structurally simple N-sulfinyl urea was found to be a highly efficient bifunctional catalyst, which allows for the development of a novel pathway for the construction of chiral β-amino nitroalkanes through enantioselective reduction of β-amino nitroolefins by trichlorosilane. High yields and excellent enantioselectivities were obtained for a broad range of β-arylamino nitroolefin substrates.
Authors:
Xiang-Wei Liu; Yan Yan; Yong-Qiang Wang; Chao Wang; Jian Sun
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-6-26
Journal Detail:
Title:  Chemistry (Weinheim an der Bergstrasse, Germany)     Volume:  -     ISSN:  1521-3765     ISO Abbreviation:  -     Publication Date:  2012 Jun 
Date Detail:
Created Date:  2012-6-27     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9513783     Medline TA:  Chemistry     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
Natural Products Research Center, Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu 610041 (P. R. China), Fax: (+86) 28-85222753; Graduate University of the Chinese Academy of Sciences, Beijing 100049 (P. R. China).
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