| Highly Enantioselective Reduction of β-Amino Nitroolefins with a Simple N-Sulfinyl Urea as Bifunctional Catalyst. | |
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MedLine Citation:
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PMID: 22736502 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Simple but effective: A structurally simple N-sulfinyl urea was found to be a highly efficient bifunctional catalyst, which allows for the development of a novel pathway for the construction of chiral β-amino nitroalkanes through enantioselective reduction of β-amino nitroolefins by trichlorosilane. High yields and excellent enantioselectivities were obtained for a broad range of β-arylamino nitroolefin substrates. |
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Authors:
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Xiang-Wei Liu; Yan Yan; Yong-Qiang Wang; Chao Wang; Jian Sun |
Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-6-26 |
Journal Detail:
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Title: Chemistry (Weinheim an der Bergstrasse, Germany) Volume: - ISSN: 1521-3765 ISO Abbreviation: - Publication Date: 2012 Jun |
Date Detail:
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Created Date: 2012-6-27 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9513783 Medline TA: Chemistry Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Copyright Information:
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Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
Affiliation:
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Natural Products Research Center, Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu 610041 (P. R. China), Fax: (+86) 28-85222753; Graduate University of the Chinese Academy of Sciences, Beijing 100049 (P. R. China). |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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