Document Detail


High energy resolution off-resonant spectroscopy at sub-second time resolution: (Pt(acac)(2)) decomposition.
MedLine Citation:
PMID:  23032154     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
We report on the decomposition of platinum acetylacetonate (Pt(acac)(2)) in hydrogen induced by flash heating. The changes in the local Pt structure were followed by high energy resolution off-resonant spectroscopy uniquely performed with sub-second time resolution. The decomposition consists of a two-step reduction process of the Pt(ii) species.
Authors:
Jakub Szlachetko; Maarten Nachtegaal; Jacinto Sá; Jean-Claude Dousse; Joanna Hoszowska; Evgeny Kleymenov; Markus Janousch; Olga V Safonova; Christian König; Jeroen A van Bokhoven
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-10-3
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2012 Oct 
Date Detail:
Created Date:  2012-10-3     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Paul Scherrer Institut, 5232 Villigen PSI, Switzerland. jakub.szlachetko@psi.ch maarten.nachtegaal@psi.ch.
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