Document Detail

High-Pressure Chemistry of Red Phosphorus and Water under Near-UV Irradiation.
MedLine Citation:
PMID:  23315979     Owner:  NLM     Status:  Publisher    
A high-pressure job: Under high-pressure conditions, within a diamond anvil cell, irradiation of red phosphorus (see scheme, orange) and water was found to lead to a reaction that gives H(2) , PH(3) , H(3) PO(2) , H(3) PO(4) , and H(3) PO(4) (H gray, O red, P orange). This reaction can be easily monitored using Raman spectroscopy and presents an interesting method for H(2) generation.
Matteo Ceppatelli; Roberto Bini; Maria Caporali; Maurizio Peruzzini
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-1-11
Journal Detail:
Title:  Angewandte Chemie (International ed. in English)     Volume:  -     ISSN:  1521-3773     ISO Abbreviation:  Angew. Chem. Int. Ed. Engl.     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-1-14     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0370543     Medline TA:  Angew Chem Int Ed Engl     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
ICCOM-CNR, Istituto di Chimica dei Composti OrganoMetallici, Consiglio Nazionale delle Ricerche, Via Madonna del Piano 10, 50019 Sesto Fiorentino, Firenze (Italy); LENS, European Laboratory for Non-Linear Spectroscopy, Firenze (Italy).,
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