| High-Pressure Chemistry of Red Phosphorus and Water under Near-UV Irradiation. | |
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MedLine Citation:
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PMID: 23315979 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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A high-pressure job: Under high-pressure conditions, within a diamond anvil cell, irradiation of red phosphorus (see scheme, orange) and water was found to lead to a reaction that gives H(2) , PH(3) , H(3) PO(2) , H(3) PO(4) , and H(3) PO(4) (H gray, O red, P orange). This reaction can be easily monitored using Raman spectroscopy and presents an interesting method for H(2) generation. |
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Authors:
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Matteo Ceppatelli; Roberto Bini; Maria Caporali; Maurizio Peruzzini |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2013-1-11 |
Journal Detail:
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Title: Angewandte Chemie (International ed. in English) Volume: - ISSN: 1521-3773 ISO Abbreviation: Angew. Chem. Int. Ed. Engl. Publication Date: 2013 Jan |
Date Detail:
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Created Date: 2013-1-14 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 0370543 Medline TA: Angew Chem Int Ed Engl Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Copyright Information:
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Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
Affiliation:
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ICCOM-CNR, Istituto di Chimica dei Composti OrganoMetallici, Consiglio Nazionale delle Ricerche, Via Madonna del Piano 10, 50019 Sesto Fiorentino, Firenze (Italy); LENS, European Laboratory for Non-Linear Spectroscopy, Firenze (Italy). matteo.ceppatelli@iccom.cnr.it, ceppa@lens.unifi.it. |
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