Document Detail

Hexa-kis-(dimethyl sulfoxide-κO)calcium μ(6)-oxido-dodeca-kis-μ(2)-oxido-hexa-oxido-hexa-tungstate(VI).
Jump to Full Text
MedLine Citation:
PMID:  22590179     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
In the title compound, [Ca(C(2)H(6)OS)(6)][W(6)O(19)], the cation and anion both have a crystallographically imposed centre of symmetry. The Ca(II) atom in the cation is coordinated by six O atoms from six dimethyl sulfoxide ligands in a distorted octa-hedral geometry. The [W(6)O(19)](2-) isopolyanion possesses the well-known Lindqvist structure in which each W(VI) atom is coordinated by four μ(2)-O, one terminal O and one μ(6)-O atom.
Authors:
Jinfang Zhang
Related Documents :
1752239 - The electrophoretic properties of a dna cube and its substructure catenanes.
25051159 - Physicochemical and functional characterization of the collagen-polyvinylpyrrolidone co...
18946669 - The cyanide hydratase from neurospora crassa forms a helix which has a dimeric repeat.
23340979 - Syntheses, structure diversity and properties of complexes with 4-acyl pyrazolone salic...
20101089 - A list of organic kryptoracemates.
22626499 - Magnetic nanosized {m(ii)(24)}-wheel-based (m = co, ni) coordination polymers.
22651219 - Photoinduced charge transfer in short-distance ferrocenylsubphthalocyanine dyads.
11674629 - Highly conjugated molecules from dibromonaphthyl derivatives and 4-vinylpyridine or 4-a...
22715459 - Efficient hydrogen storage with the combination of lightweight mg/mgh(2) and nanostruct...
Publication Detail:
Type:  Journal Article     Date:  2012-04-28
Journal Detail:
Title:  Acta crystallographica. Section E, Structure reports online     Volume:  68     ISSN:  1600-5368     ISO Abbreviation:  Acta Crystallogr Sect E Struct Rep Online     Publication Date:  2012 May 
Date Detail:
Created Date:  2012-05-16     Completed Date:  2012-10-02     Revised Date:  2013-02-27    
Medline Journal Info:
Nlm Unique ID:  101089178     Medline TA:  Acta Crystallogr Sect E Struct Rep Online     Country:  United States    
Other Details:
Languages:  eng     Pagination:  m702     Citation Subset:  -    
Affiliation:
Molecular Materials Research Center, Scientific Research Academy, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, People's Republic of China.
Export Citation:
APA/MLA Format     Download EndNote     Download BibTex
MeSH Terms
Descriptor/Qualifier:
Comments/Corrections

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine

Full Text
Journal Information
Journal ID (nlm-ta): Acta Crystallogr Sect E Struct Rep Online
Journal ID (iso-abbrev): Acta Crystallogr Sect E Struct Rep Online
Journal ID (publisher-id): Acta Cryst. E
ISSN: 1600-5368
Publisher: International Union of Crystallography
Article Information
Download PDF
A full version of this article is available from Crystallography Journals Online.© Jinfang Zhang 2012
open-access:
Received Day: 13 Month: 4 Year: 2012
Accepted Day: 24 Month: 4 Year: 2012
collection publication date: Day: 01 Month: 5 Year: 2012
Electronic publication date: Day: 28 Month: 4 Year: 2012
pmc-release publication date: Day: 28 Month: 4 Year: 2012
Volume: 68 Issue: Pt 5
First Page: m702 Last Page: m702
ID: 3344417
PubMed Id: 22590179
Publisher Id: rz2743
DOI: 10.1107/S1600536812018338
Coden: ACSEBH
Publisher Item Identifier: S1600536812018338

Hexa­kis­(dimethyl sulfoxide-κO)calcium μ6-oxido-dodeca­kis-μ2-oxido-hexa­oxido­hexa­tungstate(VI) Alternate Title:[Ca(C2H6OS)6][W6O19]
Jinfang Zhanga*
aMolecular Materials Research Center, Scientific Research Academy, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, People’s Republic of China
Correspondence: Correspondence e-mail: zjf260@ujs.edu.cn

Related literature  

For the in situ synthetic method, see: Xu et al. (2010); Ni et al. (2009).[Chemical Structure ID: scheme1]


Experimental  
Crystal data  

  • [Ca(C2H6OS)6][W6O19]
  • Mr = 1915.95
  • Triclinic,
  • a = 8.1871 (16) Å
  • b = 11.352 (2) Å
  • c = 11.378 (2) Å
  • α = 84.53 (3)°
  • β = 73.15 (3)°
  • γ = 74.02 (3)°
  • V = 972.8 (3) Å3
  • Z = 1
  • Mo Kα radiation
  • μ = 18.20 mm−1
  • T = 293 K
  • 0.21 × 0.15 × 0.13 mm

Data collection  

  • Rigaku Saturn724+ diffractometer
  • Absorption correction: multi-scan (CrystalClear; Rigaku, 2008) Tmin = 0.047, Tmax = 0.094
  • 8635 measured reflections
  • 3507 independent reflections
  • 3072 reflections with I > 2σ(I)
  • Rint = 0.034

Refinement  

  • R[F2 > 2σ(F2)] = 0.023
  • wR(F2) = 0.047
  • S = 0.98
  • 3507 reflections
  • 229 parameters
  • H-atom parameters constrained
  • Δρmax = 1.05 e Å−3
  • Δρmin = −1.19 e Å−3

Data collection: CrystalClear (Rigaku, 2008); cell refinement: CrystalClear; data reduction: CrystalClear; program(s) used to solve structure: SHELXTL (Sheldrick, 2008); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.


Supplementary Material

Crystal structure: contains datablock(s) I, global. DOI: 10.1107/S1600536812018338/rz2743sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536812018338/rz2743Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report


Notes

fnu1Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: RZ2743).

This work was supported by the Natural Science Foundation of Jiangsu High School (10KJB430005) and the Foundation of Jiangsu University (08JDG036).

supplementary crystallographic information
Comment

The in situ synthetic method has been widely applied to constructing new compounds (Xu et al., 2010, Ni et al., 2009). In the present paper, the in situ reaction between tetrathiotungstate and calcium nitrate in DMSO to form the title compound is reported. The (W6O19)2- isopolyanion was achieved by the reaction between (WS4)2- and H2O in DMSO solution.

In the cation of the title compound (Fig. 1), the Ca2+ ion is bonded by six O atoms from six DMSO ligands in a distorted octahedral coordination geometry. The (W6O19)2- (Fig. 2) shows the usual cage-shaped Lindqvist structure, where each W atom is coordinated by four µ2-O, one terminal O and one µ6-O atoms. The W—O bond lengths involving the µ6-O atoms [2.3255 (8)–2.3292 (6) Å] are obviously longer than those observed for the µ2-O [1.905 (4)–1.934 (4) Å] and terminal [1.696 (4)–1.703 (4) Å] oxygen atoms.

Experimental

Calcium nitrate (1 mmol) was added to a solution of [NH4]2WS4 (1 mmol in 5 ml DMSO) with thorough stir for 30 minutes. After filtration, the orange filtrate was carefully laid on the surface with 8 ml i-PrOH. Colourless block crystals were obtained after about one month.

Refinement

H atoms were positioned geometrically and refined using a riding model, with C—H = 0.96 Å and with Uiso(H) = 1.5Ueq(C).

Figures
Crystal data
Data collection
Refinement
Special details
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)
Atomic displacement parameters (Å2)
Geometric parameters (Å, º)

Symmetry code: (i) −x+1, −y, −z.


References
Ni, W. X., Li, M., Zhan, S. Z., Hou, J. Z. & Li, D. (2009). Inorg. Chem.48, 1433–1441.
Rigaku (2008). CrystalClear Rigaku Corporation, Tokyo, Japan.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122.
Xu, F., Huang, W. & You, X. Z. (2010). Dalton Trans.39, 10652–10658.

Figures

[Figure ID: Fap1]
Fig. 1. 

The molecular structure of the cation in the title compound, with 30% probability displacement ellipsoids. H atoms have been omitted. Symmetry code: (i) -x, 1 - y, 1 - z.



[Figure ID: Fap2]
Fig. 2. 

The molecular structure of the anion in the title compound, with 30% probability displacement ellipsoids. Symmetry code: (i) 1 - x, -y, -z.



Tables
[TableWrap ID: d1e200]
[Ca(C2H6OS)6][W6O19] Z = 1
Mr = 1915.95 F(000) = 868
Triclinic, P1 Dx = 3.270 Mg m3
Hall symbol: -P 1 Mo Kα radiation, λ = 0.71073 Å
a = 8.1871 (16) Å Cell parameters from 4353 reflections
b = 11.352 (2) Å θ = 3.7–29.0°
c = 11.378 (2) Å µ = 18.20 mm1
α = 84.53 (3)° T = 293 K
β = 73.15 (3)° Block, colourless
γ = 74.02 (3)° 0.21 × 0.15 × 0.13 mm
V = 972.8 (3) Å3

[TableWrap ID: d1e340]
Rigaku Saturn724+ diffractometer 3507 independent reflections
Radiation source: fine-focus sealed tube 3072 reflections with I > 2σ(I)
Graphite monochromator Rint = 0.034
ω scans θmax = 25.4°, θmin = 3.7°
Absorption correction: multi-scan (CrystalClear; Rigaku, 2008) h = −9→9
Tmin = 0.047, Tmax = 0.094 k = −12→13
8635 measured reflections l = −13→12

[TableWrap ID: d1e454]
Refinement on F2 Primary atom site location: structure-invariant direct methods
Least-squares matrix: full Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.023 Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.047 H-atom parameters constrained
S = 0.98 w = 1/[σ2(Fo2) + (0.0163P)2] where P = (Fo2 + 2Fc2)/3
3507 reflections (Δ/σ)max = 0.001
229 parameters Δρmax = 1.05 e Å3
0 restraints Δρmin = −1.19 e Å3

[TableWrap ID: d1e608]
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

[TableWrap ID: d1e707]
x y z Uiso*/Ueq
Ca1 0.0000 0.5000 0.5000 0.0163 (4)
S1 −0.2595 (2) 0.38529 (14) 0.35230 (14) 0.0203 (3)
S2 0.2007 (2) 0.23054 (14) 0.63729 (14) 0.0206 (3)
S3 0.3557 (2) 0.47593 (14) 0.21704 (13) 0.0205 (4)
O1 −0.2315 (5) 0.4680 (4) 0.4393 (3) 0.0232 (10)
O2 0.0581 (5) 0.3034 (4) 0.5797 (4) 0.0250 (10)
O3 0.2119 (5) 0.4354 (4) 0.3150 (3) 0.0224 (10)
C1 −0.1301 (9) 0.4158 (6) 0.2049 (5) 0.0302 (16)
H1A −0.1824 0.4963 0.1777 0.045*
H1B −0.1247 0.3562 0.1485 0.045*
H1C −0.0129 0.4115 0.2085 0.045*
C2 −0.1315 (9) 0.2352 (6) 0.3743 (6) 0.0293 (16)
H2A −0.1852 0.2032 0.4529 0.044*
H2B −0.0142 0.2379 0.3713 0.044*
H2C −0.1259 0.1831 0.3107 0.044*
C3 0.1723 (8) 0.0790 (5) 0.6536 (6) 0.0251 (15)
H3A 0.0671 0.0769 0.7180 0.038*
H3B 0.2726 0.0233 0.6737 0.038*
H3C 0.1619 0.0553 0.5779 0.038*
C4 0.4000 (8) 0.2041 (6) 0.5156 (6) 0.0321 (17)
H4A 0.4348 0.2792 0.4944 0.048*
H4B 0.3812 0.1750 0.4453 0.048*
H4C 0.4913 0.1439 0.5415 0.048*
C5 0.2577 (9) 0.5451 (6) 0.0969 (5) 0.0299 (16)
H5A 0.2362 0.4830 0.0561 0.045*
H5B 0.3366 0.5856 0.0388 0.045*
H5C 0.1480 0.6039 0.1314 0.045*
C6 0.3767 (9) 0.6117 (6) 0.2698 (6) 0.0290 (16)
H6A 0.4292 0.5919 0.3368 0.044*
H6B 0.2619 0.6676 0.2970 0.044*
H6C 0.4502 0.6492 0.2041 0.044*
W1 0.29354 (3) 0.17964 (2) −0.02810 (2) 0.01538 (7)
W2 0.34391 (3) −0.00577 (2) 0.20593 (2) 0.01614 (8)
W3 0.66800 (3) 0.11373 (2) 0.04884 (2) 0.01671 (8)
O4 0.5000 0.0000 0.0000 0.0149 (12)
O5 0.4702 (5) 0.2359 (3) 0.0143 (3) 0.0159 (9)
O6 0.1471 (5) 0.3129 (4) −0.0504 (4) 0.0237 (10)
O7 0.2105 (5) 0.1407 (4) 0.1419 (3) 0.0182 (9)
O8 0.5081 (5) 0.0881 (4) 0.2053 (3) 0.0161 (9)
O9 0.7883 (6) 0.1969 (4) 0.0863 (4) 0.0286 (11)
O10 0.2012 (5) 0.0534 (4) −0.0611 (3) 0.0181 (9)
O11 0.4597 (5) 0.1488 (3) −0.1889 (3) 0.0178 (9)
O12 0.2325 (5) −0.0106 (4) 0.3573 (3) 0.0238 (10)
O13 0.2413 (5) −0.0963 (4) 0.1266 (3) 0.0183 (9)

[TableWrap ID: d1e1309]
U11 U22 U33 U12 U13 U23
Ca1 0.0190 (9) 0.0153 (10) 0.0149 (8) −0.0052 (8) −0.0050 (7) 0.0023 (7)
S1 0.0193 (8) 0.0218 (9) 0.0217 (8) −0.0076 (7) −0.0067 (7) 0.0002 (7)
S2 0.0207 (8) 0.0197 (9) 0.0207 (8) −0.0029 (7) −0.0075 (7) 0.0012 (7)
S3 0.0203 (8) 0.0207 (9) 0.0183 (8) −0.0051 (7) −0.0027 (7) 0.0013 (7)
O1 0.025 (2) 0.025 (3) 0.020 (2) −0.004 (2) −0.0088 (19) −0.0027 (19)
O2 0.020 (2) 0.020 (2) 0.035 (2) −0.005 (2) −0.011 (2) 0.009 (2)
O3 0.026 (2) 0.023 (3) 0.017 (2) −0.010 (2) 0.0001 (19) 0.0023 (18)
C1 0.041 (4) 0.035 (4) 0.019 (3) −0.018 (3) −0.007 (3) 0.000 (3)
C2 0.037 (4) 0.022 (4) 0.030 (4) −0.008 (3) −0.012 (3) 0.003 (3)
C3 0.027 (4) 0.018 (4) 0.031 (4) −0.006 (3) −0.009 (3) 0.003 (3)
C4 0.016 (4) 0.044 (5) 0.032 (4) −0.008 (3) −0.003 (3) 0.009 (3)
C5 0.036 (4) 0.031 (4) 0.023 (4) −0.010 (3) −0.008 (3) 0.006 (3)
C6 0.033 (4) 0.032 (4) 0.025 (4) −0.020 (3) −0.003 (3) 0.003 (3)
W1 0.01630 (14) 0.01265 (14) 0.01563 (13) −0.00101 (10) −0.00495 (10) 0.00088 (10)
W2 0.01678 (14) 0.01716 (15) 0.01205 (13) −0.00261 (11) −0.00237 (10) 0.00101 (10)
W3 0.01879 (14) 0.01511 (15) 0.01880 (14) −0.00643 (11) −0.00742 (10) 0.00045 (10)
O4 0.013 (3) 0.015 (3) 0.014 (3) −0.005 (2) −0.001 (2) 0.006 (2)
O5 0.022 (2) 0.011 (2) 0.014 (2) −0.0026 (18) −0.0071 (18) 0.0002 (17)
O6 0.025 (2) 0.019 (2) 0.023 (2) −0.001 (2) −0.0060 (19) 0.0046 (19)
O7 0.019 (2) 0.017 (2) 0.017 (2) −0.0013 (18) −0.0047 (18) −0.0019 (18)
O8 0.021 (2) 0.017 (2) 0.0113 (19) −0.0040 (18) −0.0053 (17) −0.0049 (17)
O9 0.031 (3) 0.027 (3) 0.037 (3) −0.015 (2) −0.015 (2) −0.004 (2)
O10 0.019 (2) 0.018 (2) 0.020 (2) −0.0067 (18) −0.0061 (18) −0.0017 (18)
O11 0.022 (2) 0.015 (2) 0.015 (2) −0.0046 (19) −0.0057 (18) 0.0052 (17)
O12 0.028 (3) 0.027 (3) 0.011 (2) −0.004 (2) −0.0014 (19) 0.0024 (18)
O13 0.016 (2) 0.021 (2) 0.019 (2) −0.0080 (19) −0.0049 (18) 0.0077 (18)

[TableWrap ID: d1e1858]
S1—O1 1.530 (4) C6—H6C 0.9600
S1—C1 1.765 (6) W1—O6 1.701 (4)
S1—C2 1.776 (6) W1—O10 1.905 (4)
S2—O2 1.512 (4) W1—O7 1.907 (4)
S2—C4 1.780 (6) W1—O5 1.924 (4)
S2—C3 1.784 (6) W1—O11 1.934 (4)
S3—O3 1.509 (4) W1—O4 2.3258 (9)
S3—C6 1.775 (6) W2—O12 1.703 (4)
S3—C5 1.792 (6) W2—O13 1.916 (4)
C1—H1A 0.9600 W2—O11i 1.924 (4)
C1—H1B 0.9600 W2—O7 1.929 (4)
C1—H1C 0.9600 W2—O8 1.930 (4)
C2—H2A 0.9600 W2—O4 2.3255 (8)
C2—H2B 0.9600 W3—O9 1.696 (4)
C2—H2C 0.9600 W3—O10i 1.919 (4)
C3—H3A 0.9600 W3—O13i 1.926 (4)
C3—H3B 0.9600 W3—O5 1.931 (4)
C3—H3C 0.9600 W3—O8 1.931 (4)
C4—H4A 0.9600 W3—O4 2.3292 (6)
C4—H4B 0.9600 O4—W2i 2.3255 (8)
C4—H4C 0.9600 O4—W1i 2.3258 (9)
C5—H5A 0.9600 O4—W3i 2.3292 (6)
C5—H5B 0.9600 O10—W3i 1.919 (4)
C5—H5C 0.9600 O11—W2i 1.924 (4)
C6—H6A 0.9600 O13—W3i 1.926 (4)
C6—H6B 0.9600
O1—S1—C1 105.5 (3) O10—W1—O4 76.19 (12)
O1—S1—C2 106.5 (3) O7—W1—O4 76.43 (12)
C1—S1—C2 98.3 (3) O5—W1—O4 76.06 (11)
O2—S2—C4 105.3 (3) O11—W1—O4 76.15 (12)
O2—S2—C3 104.4 (3) O12—W2—O13 104.30 (18)
C4—S2—C3 98.5 (3) O12—W2—O11i 103.04 (18)
O3—S3—C6 106.8 (3) O13—W2—O11i 86.91 (16)
O3—S3—C5 106.0 (3) O12—W2—O7 104.58 (18)
C6—S3—C5 97.5 (3) O13—W2—O7 87.18 (16)
S1—C1—H1A 109.5 O11i—W2—O7 152.37 (16)
S1—C1—H1B 109.5 O12—W2—O8 102.96 (18)
H1A—C1—H1B 109.5 O13—W2—O8 152.74 (15)
S1—C1—H1C 109.5 O11i—W2—O8 86.82 (16)
H1A—C1—H1C 109.5 O7—W2—O8 86.18 (17)
H1B—C1—H1C 109.5 O12—W2—O4 179.15 (14)
S1—C2—H2A 109.5 O13—W2—O4 76.27 (11)
S1—C2—H2B 109.5 O11i—W2—O4 76.33 (11)
H2A—C2—H2B 109.5 O7—W2—O4 76.04 (11)
S1—C2—H2C 109.5 O8—W2—O4 76.47 (11)
H2A—C2—H2C 109.5 O9—W3—O10i 104.34 (19)
H2B—C2—H2C 109.5 O9—W3—O13i 104.75 (19)
S2—C3—H3A 109.5 O10i—W3—O13i 86.68 (17)
S2—C3—H3B 109.5 O9—W3—O5 103.97 (19)
H3A—C3—H3B 109.5 O10i—W3—O5 151.69 (16)
S2—C3—H3C 109.5 O13i—W3—O5 85.75 (16)
H3A—C3—H3C 109.5 O9—W3—O8 102.89 (18)
H3B—C3—H3C 109.5 O10i—W3—O8 87.37 (16)
S2—C4—H4A 109.5 O13i—W3—O8 152.35 (16)
S2—C4—H4B 109.5 O5—W3—O8 86.80 (16)
H4A—C4—H4B 109.5 O9—W3—O4 179.23 (15)
S2—C4—H4C 109.5 O10i—W3—O4 75.84 (11)
H4A—C4—H4C 109.5 O13i—W3—O4 76.00 (11)
H4B—C4—H4C 109.5 O5—W3—O4 75.85 (11)
S3—C5—H5A 109.5 O8—W3—O4 76.36 (11)
S3—C5—H5B 109.5 W2—O4—W2i 180.000 (15)
H5A—C5—H5B 109.5 W2—O4—W1i 90.19 (4)
S3—C5—H5C 109.5 W2i—O4—W1i 89.81 (4)
H5A—C5—H5C 109.5 W2—O4—W1 89.81 (4)
H5B—C5—H5C 109.5 W2i—O4—W1 90.19 (4)
S3—C6—H6A 109.5 W1i—O4—W1 180.000 (18)
S3—C6—H6B 109.5 W2—O4—W3 90.07 (3)
H6A—C6—H6B 109.5 W2i—O4—W3 89.93 (3)
S3—C6—H6C 109.5 W1i—O4—W3 89.690 (19)
H6A—C6—H6C 109.5 W1—O4—W3 90.310 (19)
H6B—C6—H6C 109.5 W2—O4—W3i 89.93 (3)
O6—W1—O10 105.04 (19) W2i—O4—W3i 90.07 (3)
O6—W1—O7 104.53 (18) W1i—O4—W3i 90.310 (19)
O10—W1—O7 87.11 (16) W1—O4—W3i 89.690 (19)
O6—W1—O5 102.69 (18) W3—O4—W3i 180.000 (12)
O10—W1—O5 152.24 (17) W1—O5—W3 117.76 (19)
O7—W1—O5 87.11 (16) W1—O7—W2 117.72 (19)
O6—W1—O11 102.88 (18) W2—O8—W3 117.10 (18)
O10—W1—O11 86.69 (16) W1—O10—W3i 118.3 (2)
O7—W1—O11 152.57 (17) W2i—O11—W1 117.33 (19)
O5—W1—O11 86.06 (16) W2—O13—W3i 117.79 (18)
O6—W1—O4 178.43 (14)
O13—W2—O4—W1i −89.97 (12) O8—W3—O4—W1 89.34 (13)
O11i—W2—O4—W1i 0.16 (12) O6—W1—O5—W3 179.93 (19)
O7—W2—O4—W1i 179.54 (12) O10—W1—O5—W3 −2.5 (4)
O8—W2—O4—W1i 90.15 (12) O7—W1—O5—W3 75.7 (2)
O13—W2—O4—W1 90.03 (12) O11—W1—O5—W3 −77.7 (2)
O11i—W2—O4—W1 −179.84 (12) O4—W1—O5—W3 −1.05 (15)
O7—W2—O4—W1 −0.46 (12) O9—W3—O5—W1 −178.2 (2)
O8—W2—O4—W1 −89.85 (12) O10i—W3—O5—W1 2.7 (4)
O13—W2—O4—W3 −179.66 (12) O13i—W3—O5—W1 77.7 (2)
O11i—W2—O4—W3 −89.53 (12) O8—W3—O5—W1 −75.7 (2)
O7—W2—O4—W3 89.85 (12) O4—W3—O5—W1 1.05 (15)
O8—W2—O4—W3 0.46 (12) O6—W1—O7—W2 −179.4 (2)
O13—W2—O4—W3i 0.34 (12) O10—W1—O7—W2 75.8 (2)
O11i—W2—O4—W3i 90.47 (12) O5—W1—O7—W2 −77.0 (2)
O7—W2—O4—W3i −90.15 (12) O11—W1—O7—W2 −1.3 (5)
O8—W2—O4—W3i −179.54 (12) O4—W1—O7—W2 −0.64 (16)
O10—W1—O4—W2 −89.87 (12) O12—W2—O7—W1 −180.0 (2)
O7—W1—O4—W2 0.47 (12) O13—W2—O7—W1 −75.9 (2)
O5—W1—O4—W2 90.83 (11) O11i—W2—O7—W1 1.9 (5)
O11—W1—O4—W2 −179.84 (12) O8—W2—O7—W1 77.6 (2)
O10—W1—O4—W2i 90.13 (12) O4—W2—O7—W1 0.64 (16)
O7—W1—O4—W2i −179.53 (12) O12—W2—O8—W3 178.7 (2)
O5—W1—O4—W2i −89.17 (11) O13—W2—O8—W3 −0.9 (5)
O11—W1—O4—W2i 0.16 (12) O11i—W2—O8—W3 76.1 (2)
O10—W1—O4—W3 −179.94 (11) O7—W2—O8—W3 −77.2 (2)
O7—W1—O4—W3 −89.60 (12) O4—W2—O8—W3 −0.63 (16)
O5—W1—O4—W3 0.77 (11) O9—W3—O8—W2 −179.6 (2)
O11—W1—O4—W3 90.10 (12) O10i—W3—O8—W2 −75.4 (2)
O10—W1—O4—W3i 0.06 (11) O13i—W3—O8—W2 2.3 (5)
O7—W1—O4—W3i 90.40 (12) O5—W3—O8—W2 76.8 (2)
O5—W1—O4—W3i −179.23 (11) O4—W3—O8—W2 0.63 (16)
O11—W1—O4—W3i −89.90 (12) O6—W1—O10—W3i 178.9 (2)
O10i—W3—O4—W2 90.26 (12) O7—W1—O10—W3i −76.8 (2)
O13i—W3—O4—W2 −179.67 (12) O5—W1—O10—W3i 1.4 (5)
O5—W3—O4—W2 −90.57 (11) O11—W1—O10—W3i 76.5 (2)
O8—W3—O4—W2 −0.46 (12) O4—W1—O10—W3i −0.09 (16)
O10i—W3—O4—W2i −89.74 (12) O6—W1—O11—W2i 178.5 (2)
O13i—W3—O4—W2i 0.33 (12) O10—W1—O11—W2i −76.8 (2)
O5—W3—O4—W2i 89.43 (11) O7—W1—O11—W2i 0.4 (5)
O8—W3—O4—W2i 179.54 (12) O5—W1—O11—W2i 76.4 (2)
O10i—W3—O4—W1i 0.06 (11) O4—W1—O11—W2i −0.22 (16)
O13i—W3—O4—W1i 90.14 (13) O12—W2—O13—W3i −179.8 (2)
O5—W3—O4—W1i 179.23 (11) O11i—W2—O13—W3i −77.1 (2)
O8—W3—O4—W1i −90.66 (13) O7—W2—O13—W3i 75.9 (2)
O10i—W3—O4—W1 −179.94 (11) O8—W2—O13—W3i −0.2 (5)
O13i—W3—O4—W1 −89.86 (13) O4—W2—O13—W3i −0.46 (16)
O5—W3—O4—W1 −0.77 (11)


Article Categories:
  • Metal-Organic Papers


Previous Document:  Tris(1,10-phenanthrolin-1-ium) hexa-cyanidoferrate(III) ethanol monosolvate trihydrate.
Next Document:  Bis(3-acetyl-pyridine-?N)diaqua-bis-(seleno-cyanato-?N)cobalt(II).