| Heterolytic cleavage of hydrogen molecule by rhodium thiolate complexes that catalyze chemoselective hydrogenation of imines under ambient conditions. | |
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MedLine Citation:
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PMID: 19824724 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
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The bis(thiolate)Rh(III) complex having a tris(3,5-dimethylpyrazolyl)borate (Tp(Me2)) coligand [Tp(Me2)Rh(SPh)(2)(MeCN)] reacts reversibly with H(2) to form the hydridothiolato complex [Tp(Me2)RhH(SPh)(MeCN)] and PhSH. The benzenedithiolate analogue [Tp(Me2)Rh(o-S(2)C(6)H(4))(MeCN)], which can also heterolytically activate H(2), catalyzes hydrogenation of imines under ambient temperature and pressure with high chemoselectivity. |
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Authors:
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Yoshiyuki Misumi; Hidetake Seino; Yasushi Mizobe |
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Publication Detail:
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Type: Journal Article; Research Support, Non-U.S. Gov't |
Journal Detail:
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Title: Journal of the American Chemical Society Volume: 131 ISSN: 1520-5126 ISO Abbreviation: J. Am. Chem. Soc. Publication Date: 2009 Oct |
Date Detail:
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Created Date: 2009-10-14 Completed Date: 2010-01-11 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 7503056 Medline TA: J Am Chem Soc Country: United States |
Other Details:
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Languages: eng Pagination: 14636-7 Citation Subset: IM |
Affiliation:
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Institute of Industrial Science, The University of Tokyo, Komaba, Meguro-ku, Tokyo 153-8505, Japan. |
Export Citation:
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| MeSH Terms | |
Descriptor/Qualifier:
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Catalysis Hydrogen / chemistry* Hydrogenation Imines / chemistry* Organometallic Compounds / chemistry* Pressure Rhodium / chemistry* Substrate Specificity Temperature |
| Chemical | |
Reg. No./Substance:
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0/Imines; 0/Organometallic Compounds; 1333-74-0/Hydrogen; 7440-16-6/Rhodium |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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