Document Detail


"Hard-Soft" Synthesis of SrCrO(3-δ) Superstructure Phases.
MedLine Citation:
PMID:  23011678     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Dense metastable phases obtained under "hard" high-pressure conditions may contain instabilities such as unusual oxidation states or coordination environments that may be partially relieved by "soft" low-temperature chemistry. The synthesis of SrCrO(2.8) and SrCrO(2.75) (right) phases from the high-pressure perovskite SrCrO(3) leads to a relaxation of the coordination around Cr(4+) from octahedral to tetrahedral.
Authors:
Angel M Arévalo-López; Jennifer A Rodgers; Mark S Senn; Falak Sher; James Farnham; William Gibbs; J Paul Attfield
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-9-26
Journal Detail:
Title:  Angewandte Chemie (International ed. in English)     Volume:  -     ISSN:  1521-3773     ISO Abbreviation:  Angew. Chem. Int. Ed. Engl.     Publication Date:  2012 Sep 
Date Detail:
Created Date:  2012-9-26     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0370543     Medline TA:  Angew Chem Int Ed Engl     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
Centre for Science at Extreme Conditions (CSEC) and School of Chemistry, University of Edinburgh, Mayfield Road, Edinburgh EH9 3JZ (UK).
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