| "Hard-Soft" Synthesis of SrCrO(3-δ) Superstructure Phases. | |
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MedLine Citation:
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PMID: 23011678 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Dense metastable phases obtained under "hard" high-pressure conditions may contain instabilities such as unusual oxidation states or coordination environments that may be partially relieved by "soft" low-temperature chemistry. The synthesis of SrCrO(2.8) and SrCrO(2.75) (right) phases from the high-pressure perovskite SrCrO(3) leads to a relaxation of the coordination around Cr(4+) from octahedral to tetrahedral. |
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Authors:
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Angel M Arévalo-López; Jennifer A Rodgers; Mark S Senn; Falak Sher; James Farnham; William Gibbs; J Paul Attfield |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-9-26 |
Journal Detail:
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Title: Angewandte Chemie (International ed. in English) Volume: - ISSN: 1521-3773 ISO Abbreviation: Angew. Chem. Int. Ed. Engl. Publication Date: 2012 Sep |
Date Detail:
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Created Date: 2012-9-26 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 0370543 Medline TA: Angew Chem Int Ed Engl Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Copyright Information:
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Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
Affiliation:
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Centre for Science at Extreme Conditions (CSEC) and School of Chemistry, University of Edinburgh, Mayfield Road, Edinburgh EH9 3JZ (UK). |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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