Document Detail


Gyrinidal: a sesquiterpenoid aldehyde from the defensive glands of gyrinid beetles.
MedLine Citation:
PMID:  4504334     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Three species of gyrinid beetles (Gyrinus ventralis, Dineutes hornii, and D. serrulatus) have been found to produce the nor-sesquiterpenoid aldehyde gyrinidal in the secretion of their pygidial defensive glands. This highly functionalized terpene is shown to be (E,E,E)-3,7-dimethyl-8,11-dioxo-2,6,9-dodecatrienal on the basis of spectral evidence and chemical degradation. While a very wide range of sesquiterpenoid structures occur in nature, gyrinidal appears to be the most highly oxidized acyclic sesquiterpene known.
Authors:
J Meinwald; K Opheim; T Eisner
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Proceedings of the National Academy of Sciences of the United States of America     Volume:  69     ISSN:  0027-8424     ISO Abbreviation:  Proc. Natl. Acad. Sci. U.S.A.     Publication Date:  1972 May 
Date Detail:
Created Date:  1972-08-19     Completed Date:  1972-08-19     Revised Date:  2010-09-10    
Medline Journal Info:
Nlm Unique ID:  7505876     Medline TA:  Proc Natl Acad Sci U S A     Country:  UNITED STATES    
Other Details:
Languages:  eng     Pagination:  1208-10     Citation Subset:  IM    
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MeSH Terms
Descriptor/Qualifier:
Aldehydes / analysis,  isolation & purification*,  secretion
Animal Communication
Animals
Beetles*
Chromatography, Gas
Chromatography, Thin Layer
Female
Infrared Rays
Ketones / analysis,  isolation & purification,  secretion
Magnetic Resonance Spectroscopy
Male
Mass Spectrometry
Perianal Glands / analysis*,  secretion
Spectrum Analysis
Terpenes / analysis,  isolation & purification*,  secretion
Ultraviolet Rays
Chemical
Reg. No./Substance:
0/Aldehydes; 0/Ketones; 0/Terpenes
Comments/Corrections

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